Results 141 to 150 of about 131,045 (252)
Synthesis of Chromium(IV) Nitrides Through High-Spin Tetrahedral Chromium(I) Intermediates. [PDF]
Inorg ChemPanetti GB +5 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.A novel photoluminochromism (PLC, > 100 nm shifts) of carbon‐centered gold cluster bearing pyridylphosphine ligands is reported. Upon dissolution/crystallization, the greenish‐yellow emissive solids and red emissive solution may reversibly convert into each other, and such processes are prohibited when utilizing pyridyl N‐heterocyclic carbene (NHC) as ...
Zhen Lei +8 more
wiley +1 more source
Electronic and Steric Effects of the ProPhos Ligand Family for Nickel-Catalyzed Suzuki-Miyaura Coupling of Heteroaromatics. [PDF]
ACS CatalYang J +5 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang +2 more
wiley +1 more source
The organophosphorus synthesis triangle: introducing methods for the missing quaternization and de-quaternization routes. [PDF]
Chem SciVetter AC +3 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Recent theoretical efforts to elucidate the origin of enantioselectivity in transition metal‐catalyzed propargylic substitution reactions are highlighted in this review. ABSTRACT In recent years, asymmetric catalytic propargylic substitution reactions have undergone remarkable development, enabling the construction of chiral carbon centers adjacent to ...
Ken Sakata, Yoshiaki Nishibayashi
wiley +1 more source
"Blebbing" of a Gold Nanocluster by Dioxygen Insertion into Thiolate Staples during Self-Photooxidation. [PDF]
J Phys Chem AEssang S, Greer A.
europepmc +1 more source
Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance
Chemistry – A European Journal, EarlyView.This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini +3 more
wiley +1 more source
Design and Synthesis of Planar Chiral Bisphosphine Ligands Based on Diphenyl [2.2]-Paracyclophane. [PDF]
MoleculesHuang S, Huang Y, Jin J, Gu H, Lin X.
europepmc +1 more source
Gold(I) Phosphine/Phosphido‐Borohydride Complexes
European Journal of Inorganic Chemistry, EarlyView.Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source