Disulfide Competition for Phosphine Gold(I) Thiolates: Phosphine Oxide Formation vs. Thiolate Disulfide Exchange [PDF]
Inorganics, 2015 Phosphine gold(I) thiolate complexes react with aromatic disulfides via two pathways: either thiolate–disulfide exchange or a pathway that leads to formation of phosphine oxide.
Gamage S. P. Garusinghe +5 more
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Surface Passivation with Selected Phosphine Oxide Molecules for Efficient Pure‐Blue Mixed‐Halide Perovskite Quantum Dot Light‐Emitting Diodes [PDF]
Advanced Materials Interfaces, 2023 Passivation of defects in halide perovskite using phosphine oxide or alkyl‐phosphonate has recently obtained a few remarkable achievements. However, effective application of phosphine oxide or alky‐phosphonate in passivating perovskite quantum dots (QDs)
Fang Chen +6 more
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A visible-light activated secondary phosphine oxide ligand enabling Pd-catalyzed radical cross-couplings [PDF]
Nature Communications, 2022 Ligand design is key for improving the performance in light-enabled catalytic processes. Here, the authors report the synthesis of a visible-light–activated secondary phosphine oxide ligand and apply it to Pd-catalyzed radical cross-coupling reactions.
Takahito Kuribara +2 more
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Phosphine Oxide Indenoquinoline Derivatives: Synthesis and Biological Evaluation as Topoisomerase I Inhibitors and Antiproliferative Agents [PDF]
MoleculesThe synthesis of phosphorous indenoquinolines and their biological evaluation as topoisomerase 1 (TOP1) inhibitors and antiproliferative agents were performed.
Alba Rodriguez-Paniagua +4 more
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Lanthanide phosphine oxide complexes [PDF]
Coordination Chemistry Reviews, 2017 Phosphine oxide complexes of lanthanide metal have been studied to elucidate the fundamental aspects\ud of their structural chemistry and to develop important technological applications mainly in the reprocessing\ud of nuclear fuels and in photoluminescent devices but also in other fields such as gas sorption\ud and homogeneous catalysis.
Andrew W.G. Platt
openaire +3 more sources
5-Cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinane, its phosphine oxide, and its [NiCl2L2] complex [PDF]
Acta Crystallographica Section E: Crystallographic CommunicationsThe crystal structures of 5-cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinane, C21H27N2P, and its oxidized phosphine oxide, 5-cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinan-5-one, C21H27N2OP, have primitive monoclinic symmetry (both in space group P21/m) at ...
David Esjornson +5 more
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Study of the Adsorption and Separation Behavior of Scandium and Zirconium by Trialkyl Phosphine Oxide-Modified Resins in Sulfuric and Hydrochloric Acid Media. [PDF]
ToxicsXu B +7 more
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Frontiers in Nanotechnology, 2022 We report a low-temperature colloidal synthesis of WSe2 nanocrystals from tungsten hexacarbonyl and diphenyl diselenide in trioctylphosphine oxide (TOPO).
Jessica Q. Geisenhoff +5 more
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Ortho-Phosphinoarenesulfonamide-Mediated Staudinger Reduction of Aryl and Alkyl Azides
Molecules, 2022 Conventional Staudinger reductions of organic azides are sluggish with aryl or bulky aliphatic azides. In addition, Staudinger reduction usually requires a large excess of water to promote the decomposition of the aza-ylide intermediate into phosphine ...
Xingzhuo Li +5 more
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Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection
Nanomaterials, 2023 The present work demonstrates the optimization of the ligand structure in the series of bis(phosphine oxide) and β-ketophosphine oxide representatives for efficient coordination of Tb3+ and Eu3+ ions with the formation of the complexes exhibiting high ...
Rustem Zairov +13 more
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