Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides [PDF]
Nolan T. McDougal+4 more
openalex +1 more source
Unraveling the role of ligand structure in modulating chiral europium complex luminescence
Circularly Polarized Luminescence (CPL) is a phenomenon where chiral luminescent materials emit light preferentially polarized in a specific direction. This property arises from the interaction of chiral ligands with lanthanide ions, inducing chirality ...
Dr. Md. Jahidul Islam, Md. Hafizul Islam
doaj
Crystal structure of a tris(2-amino-eth-yl)methane capped carbamoyl-methyl-phosphine oxide compound. [PDF]
Wackerle BG+3 more
europepmc +1 more source
Low-temperature superstructure of [(N,N-diisobutylcarbamoyl)methyl]octyl(phenyl)phosphine oxide (CMPO) [PDF]
Michaela Pojarová+2 more
openalex +1 more source
Intermolecular sp3C‐H Metalation of Non‐Nucleophilic Brønsted Bases Using Simple Lewis Acids
2,6‐Di‐tert‐butyl substituted pyridines (tBu2‐py) are widely used non‐nucleophilic Brønsted bases. Their ubiquity is due to their highly hindered basic site and chemically robust nature. Herein we report that simple M2X6 Lewis acids (M = Al or Ga, X = Cl, Br or I) effect intermolecular sp3C‐H metalation of tBu2‐py bases under mild conditions.
Anna Schellbach+5 more
wiley +1 more source
A Homobimetallic Frustrated Lewis Pair Cobalt Catalyst for the Methanolysis of Hydrosilanes
The bimetallic Co(I)/Co(–I) complex [Co(CO)2(κ3‐P,N,P‐PNHP)][Co(CO)4] (1) has shown excellent activities in the methanolysis of hydrosilanes, surpassing the related bimetallic Co(I)/Co(–I) complex [Co(CO)(PMe2Ph)(κ3‐P,N,P‐PNHP)][Co(CO)4] (2), the Co(II) complex [Co(Cl)2(κ3‐P,N,P‐PNHP)] (3), and the Co(I) complex [Co(CO)2(κ3‐P,N,P‐PNHP)]Cl (4).
Ana Luque-Gómez+6 more
wiley +1 more source
ABSTRACT This work investigates the development of photopolymerization‐induced phase separation (PhIPS) in methacrylate‐based photopolymers. Bisphenol A ethoxylated dimethacrylate (BisEMA) was copolymerized with urethane‐based diacrylate diluted in isobornyl acrylate (UI) under UV irradiation, using diphenyl‐(2,4,6‐trimethylbenzoyl) phosphine oxide ...
Mojtaba Ahmadi+6 more
wiley +1 more source
Solvent-dependent luminescence of eight-coordinated Eu(III) complexes with bidentate phosphine oxide [PDF]
Kohei Miyata+3 more
openalex +1 more source
Metal‐Mediated Protein Engineering within Live Cells
This review discusses how metal ions can mediate protein modification within live cells. With its easy handling, rapid solubility, and ease of internalization within the cells, metal ions can be an excellent stimulus for many organic reactions needed within an intracellular medium, which can modify proteins and lead to applications in chemistry ...
Pritam Ghosh
wiley +1 more source