Results 61 to 70 of about 19,150 (267)

Additive Manufacturing of Molecular Architecture Encoded Stretchable Polyethylene Glycol Hydrogels and Elastomers

open access: yesAdvanced Materials, EarlyView.
Bottlebrush molecular architecture prevents the crystallization of high molecular weight polyethylene glycol (PEG) based polymers, enabling highly stretchable photocurable PEG hydrogels and elastomers for high‐performance conductive solvent‐free electrolytes at room temperature and for additive manufacturing of complex architectures and multi‐material ...
Baiqiang Huang   +5 more
wiley   +1 more source

Fluctuating Curvature and Actuation in 4D Printed Asymmetric Networks by Frontal Photopolymerization

open access: yesAdvanced Materials Interfaces, EarlyView.
Asymmetric polymer networks, fabricated by frontal photopolymerization (FPP), are shown to exhibit curvature oscillations associated with monomer‐solvent exchanges during development and drying. We introduce a theoretical model for such dynamic curvature fluctuations and demonstrate the fabrication of bistable switches and self‐propelled materials that
Muhammad Ghifari Ridwan   +3 more
wiley   +1 more source

Vat Photopolymerized HEMA/HEA Hydrogels for Solvent‐Responsive Transparency and Optical Encryption

open access: yesAdvanced Optical Materials, EarlyView.
Vat‐photopolymerized HEMA/HEA hydrogels exhibit reversible transparency‐opacity switching via hydration‐induced microphase separation and solvent exchange. The printed materials enable hydration sensing, optical encryption, and information storage, while maintaining high ductility and reversible rheology.
Murad Ali   +4 more
wiley   +1 more source

Recent trends in bonding and structure of metal derivatives of phosphine chalcogenides

open access: yesDiscover Chemistry
In this review, the bonding and structures of coordination compounds of phosphine chalcogenides (P = E, E = O, S, Se, Te) with several transition and non-transition elements, reported during the period from 1990 to 2023, are described.
Tarlok Singh Lobana
doaj   +1 more source

Hydrogen-Bonded Di(hydroperoxy)alkane Adducts of the Type Cy3P=O·(HOO)2CHR (R = Alkyl)

open access: yesMolecules
Five representatives of a novel type of di(hydroperoxy)alkane adducts of phosphine oxides have been synthesized and fully characterized, including their solubility in organic solvents.
Rahym Ashirov   +3 more
doaj   +1 more source

Donor‐Substituted C(sp3)‐Bridged Phosphorus‐Heterotriangulenes as Blue Thermally Activated Delayed Fluorescence Emitters

open access: yesAdvanced Optical Materials, EarlyView.
The newly developed regioselective strategy for the para‐functionalization of C(sp3)‐bridged phosphorus‐centered heterotriangulene delivers a series of donor‐acceptor emitters exhibiting thermally activated delayed fluorescence. The carbazole‐substituted compounds feature a unique combination of high photoluminescence quantum yields up to 75%, deep ...
Maximilian Schöner   +8 more
wiley   +1 more source

Microwave-Assisted Kabachnik–Fields Reaction with Amino Alcohols as the Amine Component

open access: yesMolecules, 2019
In this paper, the microwave (MW)-assisted catalyst-free and mostly solvent-free Kabachnik−Fields reaction of amino alcohols, paraformaldehyde, and various >P(O)H reagents (dialkyl phosphites, ethyl phenyl-H-phosphinate, and secondary phosphine ...
Ádám Tajti   +4 more
doaj   +1 more source

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner   +4 more
wiley   +1 more source

VDLIN: A Deep Learning‐Based Platform for Methylcobalamin‐Inspired Immunomodulatory Compound Screening

open access: yesAdvanced Science, EarlyView.
Using the convolutional neural network model VDLIN, Co7 is identified as a promising therapeutic candidate. Co7 demonstrates distinct advantages over MCB by effectively balancing anti‐inflammatory and immune‐stimulatory functions, making it a potential novel approach for immune modulation.
Xuefei Guo   +6 more
wiley   +1 more source

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