Results 101 to 110 of about 51,028 (331)

Dinitrogen Complexes of Sulfur-Ligated Iron [PDF]

open access: yes, 2011
We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands (2-R_2PC_6H_4)_3Si (R = Ph, iPr) but have one or two phosphine
Mankad, Neal P.   +2 more
core   +1 more source

Carbon−Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers [PDF]

open access: yes, 2009
Reaction of [Re2(CO)9(NCMe)] with tri(2-thienyl)phosphine (PTh3) in refluxing cyclohexane affords three substituted dirhenium complexes: [Re2(CO)9(PTh3)] (1), [Re2(CO)8(NCMe)(PTh3)] (2), and [Re2(CO)8(PTh3)2] (3).
Begum, Noorjahan   +12 more
core   +2 more sources

Additive Manufacturing of Molecular Architecture Encoded Stretchable Polyethylene Glycol Hydrogels and Elastomers

open access: yesAdvanced Materials, EarlyView.
Bottlebrush molecular architecture prevents the crystallization of high molecular weight polyethylene glycol (PEG) based polymers, enabling highly stretchable photocurable PEG hydrogels and elastomers for high‐performance conductive solvent‐free electrolytes at room temperature and for additive manufacturing of complex architectures and multi‐material ...
Baiqiang Huang   +5 more
wiley   +1 more source

Combustive approach for measuring total volatile phosphorus content in landfill gas [PDF]

open access: yes, 2005
A technique was developed to measure the total gaseous phosphorus content in biogas. The amount of air needed for a neutral to oxidising flame was mixed with the biogas.
ROELS, Joris   +2 more
core  

Rewriting Polymer Fate via Chemomechanical Coupling

open access: yesAdvanced Materials, EarlyView.
This work introduces a life‐like “living” polymer platform that can grow, degrow, and reprogram its properties after fabrication. By integrating mass transport, reversible polymerization, and controlled catalysis, the material achieves on‐demand changes in size, shape, and mechanical properties.
Jiahe Huang   +9 more
wiley   +1 more source

Gold phosphide complexes [PDF]

open access: yes, 2007
6 pages, 9 schemes, 6 figures.The vast majority of gold complexes with five group-element donor ligands contain tertiary phosphines, although compounds with amine, arsine or stibine ligands are also known.
Fernández, Eduardo J.   +2 more
core   +1 more source

Holographic Whole‐Object Photopolymerization Preserving Director Alignment in Liquid Crystalline Actuators

open access: yesAdvanced Materials, EarlyView.
Holographic microlithography enables the fabrication of fully connected 3D liquid crystalline structures in a single exposure. The process maintains precise control over the director orientation within the entire object, preventing local director distortions typically observed in sequential printing.
Lovish Gulati   +8 more
wiley   +1 more source

phosphines

open access: yes, 2014
Citation: 'phosphines' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.P04553 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Nitroxide‐Mediated Photo‐Polymerization: A Swiss Army Knife for Microfluidic Design

open access: yesAdvanced Materials Technologies, EarlyView.
This article illustrates the application of NMP2 to the rapid (less than 1 h) photostructuring and sealing of model structures intended for microfluidic applications. Remarkably, the careful design of resin composition allows completing these steps by simply spreading bare monomer (i.e., no added photoinitiator) on top of the bottom layer embedding ...
Carlo Gonzato   +5 more
wiley   +1 more source

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