Results 101 to 110 of about 95,078 (410)

Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines

open access: yesJournal of the American Chemical Society, 2016
Catalytic synthesis of nonracemic P-chiral phosphine derivatives remains a significant challenge. Here we report Cu-catalyzed enantioselective arylation of secondary phosphine oxides with diaryliodonium salts for the synthesis of tertiary phosphine ...
R. Beaud, Robert J. Phipps, M. Gaunt
semanticscholar   +1 more source

Transmembrane Activation of Catalysis and Protein Refolding in Synthetic Cells by Enzymes and Nanozymes

open access: yesAdvanced Functional Materials, EarlyView.
Synthetic cells are engineered herein to respond to an external chemical messenger by the activation of intracellular catalysis. The chemical messenger molecules are catalytically generated by an extracellular enzyme or a mineral surface, whereas the intracellular catalysis emerges via direct enzyme activation or via protein refolding.
Dante G. Andersen   +5 more
wiley   +1 more source

Supported Binuclear Gold Phosphine Complexes as CO Oxidation Catalysts: Insights into the Formation of Surface‐Stabilized Au Particles

open access: yesSmall Science
Atomically precise gold phosphine complexes as precursors for supported Au catalysts tested in CO oxidation are presented. Using a variety of analytical techniques, including in situ and operando X‐ray absorption spectroscopy, it is discovered that minor
Fabian Rang   +5 more
doaj   +1 more source

Synthesis and Coordination Behavior of a Flexible Bis(phosphinoferrocene) Ligand

open access: yesMolecules, 2018
A symmetrical flexible bis(phosphinoferrocene) derivative, viz. bis[1′-(diphenylphosphino)ferrocenyl]methane (1), was prepared and studied as a ligand in Pd(II) and Au(I) complexes.
Jiří Schulz   +3 more
doaj   +1 more source

Gold amides as anticancer drugs: synthesis and activity studies [PDF]

open access: yes, 2013
Modular gold amide chemotherapeutics: Access to modern chemotherapeutics with robust and flexible synthetic routes that are amenable to extensive customisation is a key requirement in drug synthesis and discovery.
Amagai   +34 more
core   +1 more source

Perovskite Light‐Emitting Diodes with Quantum Wires and Nanorods

open access: yesAdvanced Materials, EarlyView.
This review focuses on low‐dimensional perovskite materials and discusses their applications in light‐emitting diodes (LEDs). Special attention is given to the introduction of perovskite quantum wires and nanorods, two unique types of one‐dimensional (1D) materials, and their interesting optoelectronic properties.
Qianpeng Zhang   +11 more
wiley   +1 more source

Atroposelective hydroarylation of biaryl phosphines directed by phosphorus centres

open access: yesNature Communications, 2023
Prized for their ability to generate chemical complexity rapidly, catalytic carbon–hydrogen (C–H) activation and functionalization reactions have enabled a paradigm shift in the standard logic of synthetic chemistry.
Zexian Li   +7 more
doaj   +1 more source

The Deepest Blue: Major Advances and Challenges in Deep Blue Emitting Quasi‐2D and Nanocrystalline Perovskite LEDs

open access: yesAdvanced Materials, EarlyView.
In this review, the recent development of deep‐blue (≤465 nm) perovskite light‐emitting diodes (PeLEDs) are summarized, using different perovskite nanomaterials, including nanocrystals (NCs), quantum dots (QDs), nanoplatelets (NPLs), quasi‐2D thin film, 3D bulk thin film, as well as lead‐free perovskite nanomaterials.
Pui Kei Ko   +6 more
wiley   +1 more source

Catalytic Wittig and aza-Wittig reactions

open access: yesBeilstein Journal of Organic Chemistry, 2016
This review surveys the literature regarding the development of catalytic versions of the Wittig and aza-Wittig reactions. The first section summarizes how arsenic and tellurium-based catalytic Wittig-type reaction systems were developed first due to the
Zhiqi Lao, Patrick H. Toy
doaj   +1 more source

A Novel Bis(phosphido)pyridine [PNP]^(2−) Pincer Ligand and Its Potassium and Bis(dimethylamido)zirconium(IV) Complexes [PDF]

open access: yes, 2010
A novel PNP bis(secondary phosphine)pyridine pincer ligand, 2,6-bis(2-(phenylphosphino)phenyl)pyridine, has been prepared in high yield, and the properties of the doubly deprotonated form as a ligand in K_4(PNP)_2(THF)_6 and (PNP)Zr(NMe_2)_2 have been ...
Bercaw, John E., Winston, Matthew S.
core   +1 more source

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