Results 161 to 170 of about 95,078 (410)

A Paraffin‐Based Photoresin: 3D Printing of Paraffin for Encapsulation‐Free Shape‐Stabilized Paraffin‐Based Phase Change Materials

open access: yesAdvanced Materials Technologies, EarlyView.
A novel approach for fabricating shape‐stabilized paraffin‐based phase change materials via digital light processing 3D printing is demonstrated. The printed components contain up to 60 wt.% paraffin within elastomeric polymer networks, exhibiting excellent shape stability and stretchability.
Swathi Krishna Subhash   +9 more
wiley   +1 more source

Phosphine Catalyzed Michael-Type Additions: The Synthesis of Glutamic Acid Derivatives from Arylidene-α-amino Esters

open access: yesMolecules
The reaction of arylidene-α-amino esters with electrophilic alkenes to yield Michael-type addition compounds is optimized using several phosphines as organocatalysts. The transformation is very complicated due to the generation of several final compounds,
Lesly V. Rodríguez-Flórez   +6 more
doaj   +1 more source

Metal-Free Reduction of Phosphine Oxides Using Polymethylhydrosiloxane

open access: yesInorganics, 2016
A simple protocol is presented here for the use of inexpensive polymethylhydrosiloxane (PMHS), a waste product of the silicon industry, as stoichiometric reducing agent for phosphine oxides to phosphines, a highly desirable reaction to recover P-based ...
Emmanuel Nicolas   +6 more
doaj   +1 more source

Enhanced Stability of Cd‐Free Quantum Dot Light‐Emitting Diodes via Yttrium Acetate‐Modified ZnMgO: Suppressing Mg Migration

open access: yesAdvanced Optical Materials, EarlyView.
A surface passivation strategy using yttrium acetate to suppress Mg ion migration from the ZnMgO electron transport layer is proposed. This treatment restores oxygen vacancies on the ZnMgO surface, enhancing device stability. The Cd‐free quantum dot light‐emitting diodes demonstrate a 65.5% increase in operational lifetime with an external quantum ...
Hansol Choi   +3 more
wiley   +1 more source

Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

open access: yes, 2015
We investigated the potential application of experimentally characterized low-valent silicon compounds as transition metal ligands by computing the most important ligand properties, σ-donor and π-acceptor ability, ligand-to-metal charge transfer, and ...
Z. Benedek, Tibor Szilvási
semanticscholar   +1 more source

Thermally Activated Delayed Fluorescence and Beyond. Photophysics and Material Design Strategies.

open access: yesAdvanced Photonics Research, EarlyView.
Photophysical properties of TADF molecules are determined by characteristic parameters that are discussed in detail(. Moreover, using femtosecond time‐resolved spectroscopy, quantum mechanical considerations, and state‐of‐art calculations, deeper understanding allows us to design breakthrough Cu(I) and organic TADF‐ OLED materials. For the latter ones,
Hartmut Yersin, Uwe Monkowius
wiley   +1 more source

HENRI FRANÇOIS GAL

open access: yesRevista CENIC Ciencias Químicas, 2023
Henri François Gal (1839-1897), a French chemist who studied in detail the chemical reactions of acid anhydrides, acetyl bromide and chloride, ethers, organic cyanates, organometallic compounds, strychnine and other natural extracts.
Jaime Wisniak
doaj  

Illuminating the Path of Rearrangement: Visible Light‐Driven Pd‐Catalyzed Substituted Olefins Synthesis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Pd‐catalyzed reactions are among the most straightforward and efficient methods to proficiently build Csp2‐Csp2 bonds. Nevertheless, thermal activation remains mandatory in most cases, which may decrease the compatibility with sensitive functional groups.
Jenifer Sharshonov   +7 more
wiley   +1 more source

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