Results 11 to 20 of about 76,679 (335)

Mild Reduction of Phosphine Oxides with Phosphites To Access Phosphines.

Angewandte Chemie International Edition, 2017
A new method for the iodine-catalyzed reduction of phosphine oxides with phosphites at room temperature is reported. The mild reaction conditions, scalability, and simple purification requirements render it a method of choice for the large-scale ...
Peng Li, R. Wischert, Pascal Métivier
semanticscholar   +4 more sources

[μ-1,2-Bis(dipheylphosphino)ethane-κ²P,P’]bis(3-mercapto-1,2-propanediolato-κS-gold(I))

Molbank, 2023
A new dinuclear gold(I) complex, possessing a bridging diphosphine ligand (1,2-bis(diphenylphosphino)ethane) and two terminal thiol ligands (1-thioglycerol), was synthesized and fully characterized by IR, 1H and 31P NMR, fluorescence, ESI-mass, and ...
Taichi Baba, Nobuto Yoshinari
doaj   +1 more source

Analysis of the Distribution of Total Phosphine and the Characteristics of Phosphine Poisoning in 29 Victims

Fayixue Zazhi, 2022
ObjectiveTo study the distribution of total phosphine in phosphine poisoning victims and summarize the characteristics of phosphine poisoning cases.MethodsThe phosphine and its metabolites in the biological samples of 29 victims in 16 phosphine poisoning
YAN Hui, DU Meng, QIAO Zheng, XIANG Ping, SHEN Bao-hua, SHEN Min, LIU Wei   +6 more
doaj   +1 more source

P-Stereogenic diamondoid phosphines

Журнал органічної та фармацевтичної хімії, 2020
Despite diamondoid phosphines have found many synthetic applications and are even available commercially the chemistry of chiral diamondoid phosphines remains largely unexplored. Aim. To develop the convenient preparative method for the preparation of
Kateryna D. Butova, Vladislav V. Bahonsky, Raisa I. Yurchenko, Maryna M. Moroz, Andrey A. Fokin   +4 more
doaj   +1 more source

Enantiodivergent Formation of C-P Bonds: Synthesis of P-Chiral Phosphines and Methyl-phosphonate Oligonucleotides.

Journal of the American Chemical Society, 2020
Phosphorous Incorporation (PI, abbreviated Π) reagents for the modular, scalable, and stereospecific synthesis of chiral phosphines and methyl-phosphonate nucleotides are reported.
Dongmin Xu, Nazaret Rivas-Bascón, N. Padial, Kyle W. Knouse, B. Zheng, Julien C. Vantourout, Michael A. Schmidt, Martin D. Eastgate, P. Baran   +8 more
semanticscholar   +1 more source

Phosphine Organocatalysis [PDF]

Chemical Reviews, 2018
The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a phosphine to an electrophilic starting material, producing a reactive zwitterionic intermediate, generally under mild conditions. In this Review, we classify nucleophilic phosphine catalysis reactions in terms of their electrophilic components. In the majority of
Hongchao Guo, Yi Chiao Fan, Zhanhu Sun, Yang Wu, Ohyun Kwon   +4 more
openaire   +4 more sources

Inhibition of Cancer Cell Proliferation and Bacterial Growth by Silver(I) Complexes Bearing a CH₃-Substituted Thiadiazole-Based Thioamide

Molecules, 2023
Ag(I) coordination compounds have recently attracted much attention as antiproliferative and antibacterial agents against a wide range of cancer cell lines and pathogens.
Despoina Varna, Elena Geromichalou, Georgia Karlioti, Rigini Papi, Panagiotis Dalezis, Antonios G. Hatzidimitriou, George Psomas, Theodora Choli-Papadopoulou, Dimitrios T. Trafalis, Panagiotis A. Angaridis   +9 more
doaj   +1 more source

CONFIRMATION OF CIRCUMSTELLAR PHOSPHINE [PDF]

The Astrophysical Journal, 2014
Accepted for publication in ApJ ...
Marcelino Agúndez, D. Teyssier, Leen Decin, Leen Decin, José Cernicharo, Pierre Encrenaz   +5 more
openaire   +7 more sources

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

Chemistry, 2020
Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh ...
P. Arockiam, Ulrich Lennert, C. Graf, Robin Rothfelder, Daniel J. Scott, Tillmann G. Fischer, K. Zeitler, R. Wolf   +7 more
semanticscholar   +1 more source

Diametric calix[6]arene-based phosphine gold(I) cavitands

Beilstein Journal of Organic Chemistry, 2022
We report the synthesis and characterization, in low polarity solvents, of a novel class of diametric phosphine gold(I) cavitands characterized by a 1,2,3-alternate geometry. Preliminary catalytic studies were performed on a model cycloisomerization of 1,
Gabriele Giovanardi, Andrea Secchi, Arturo Arduini, Gianpiero Cera   +3 more
doaj   +1 more source