Results 231 to 240 of about 51,028 (331)

Exploring Indium Teflates: From Neutral In(OTeF5)3(THF)3 to Anionic Complexes [In(OTeF5)4(THF)2]– and [In(OTeF5)6]3–

open access: yesChemistryEurope, EarlyView.
The study examines the coordination chemistry of indium teflate complexes, showing the progression from [In(OTeF5)3(THF)3] to the anionic species [In(OTeF5)4(THF)2]– and [In(OTeF5)6]3–. Systematic ligand substitution and anion formation reveal increasing teflate coordination, highlighting structural evolution, Lewis acidity modulation, and ...
Djamila Azrou   +7 more
wiley   +1 more source

Cationic NHC‐Phosphine Iridium Complexes: Highly Active Catalysts for Base‐Free Hydrogenation of Ketones

open access: hybrid, 2020
Xu Quan   +6 more
openalex   +1 more source

Aluminum versus Gallium: Differences in Bis(bis(trimethylsilyl)methyl) Element Halides, Hydrides, and Oxygen‐Bridged E/P Frustrated Lewis Pairs

open access: yesChemistryEurope, EarlyView.
Reacting Bis2GaBr (Bis = CH(SiMe3)2) with Bis2AlH selectively yields Bis2GaH, a monomeric hydride in solution, characterized by diffusion ordered spectroscopy NMR, infrared spectroscopy and indirectly via hydrogallation. A one‐pot route enables frustrated Lewis pairs Bis2EOPtBu2 (E = Al, Ga), with the gallium analog splitting H2 and showing a dynamic ...
Julian Buth   +7 more
wiley   +1 more source

One‐Pot Ruthenium‐Catalyzed Synthesis of Benzyl/Allyl‐Halide Substituted (dihydro)naphthalenes via Radical Benzannulation

open access: yesChemistryEurope, EarlyView.
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen   +9 more
wiley   +1 more source

Correction: Phosphine-catalyzed Friedel–Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes

open access: hybrid, 2017
Tao Zhou   +9 more
openalex   +2 more sources

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