Results 21 to 30 of about 51,028 (331)
Nature Communications, 2019 Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of ...
Dingyi Wang +6 more
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Organics, 2021 Organophosphorus compounds with stereogenic phosphorus and carbon atoms have received increasing attention. In this regards, primary phosphines with a stereogenic carbon atom adjacent to the phosphorus atom were synthesized by the reduction in ...
Toshiaki Murai +5 more
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Phosphonate–Phosphinate Rearrangement
The Journal of Organic Chemistry, 2015 LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement).
Qian, Renzhe +2 more
openaire +2 more sources
New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I) [PDF]
, 1971 The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)_2(CO)_2(PR_3)]–, [Co(CN)_2(CO)(PR_3)_2]–, and [Co(CN)(CO)_2(PR_3)_2], prepared by the reactions of tertiary phosphines (PR_3) with [Co(CN)_3 ...
Bercaw, John +2 more
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Journal of Taibah University for Science, 2020 Considering the increasing incidence of fatal aluminium phosphide (ALP) poisoning and its toxicological aspects and also the paucity of our knowledge concerning the ALP effect on adipose tissue and adipokines, the present study aimed to assess the effect
Zoya Tahergorabi +5 more
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Intramolecular Phosphine-Promoted Knoevenagel Based Redox-Reaction
Molecules, 2022 A Knoevenagel based redox-reaction promoted by intramolecular phosphine sources is presented for the first time. The influence of different diketones, aldehydes, bases and acids was investigated. The effects of different substituents were evaluated based
Niklas Feuge +3 more
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Reactions of HNO with Metal Porphyrins: Underscoring the Biological Relevance of HNO [PDF]
, 2014 Azanone (1 HNO, nitroxyl) shows interesting yet poorly understood chemical and biological effects. HNO has some overlapping properties with nitric oxide (NO), sharing its biological reactivity toward heme proteins, thiols, and oxygen.
Bikiel, Damian Ezequiel +4 more
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Sensing Organophosphorus Compounds with SWCNT Films
Sensors, 2021 Promising electrical properties of single-walled carbon nanotubes (SWCNTs) open a spectrum of applications for this material. As the SWCNT electronic characteristics respond well to the presence of various analytes, this makes them highly sensitive ...
Mika Sahlman +2 more
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Phosphine Functionalization of GaAs(111)A Surfaces [PDF]
, 2008 Phosphorus-functionalized GaAs surfaces have been prepared by exposure of Cl-terminated GaAs(111)A surfaces to triethylphosphine (PEt3) or trichlorophosphine (PCl3), or by the direct functionalization of the native-oxide terminated GaAs(111)A surface ...
Biteen, Julie S. +5 more
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Preparation of phosphines through C–P bond formation
Beilstein Journal of Organic Chemistry, 2014 Phosphines are an important class of ligands in the field of metal-catalysis. This has spurred the development of new routes toward functionalized phosphines.
Iris Wauters +2 more
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