Results 301 to 310 of about 95,078 (410)

Mechanochemistry‐Driven Borrowing Hydrogen Processes for Ru‐Catalyzed N‐Alkylation: A Pathway to Enhanced Sustainability and Efficiency

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents the first mechanochemical borrowing hydrogenation (BH) strategy, offering a direct and efficient route to N‐alkylated amines and heterocycles. This solvent‐free approach overcomes many challenges associated with conventional solution‐based syntheses, such as toxic reagents, inert atmospheres, high temperatures, lengthy reaction ...
Sourav Behera   +5 more
wiley   +1 more source

Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C‒F and C‒O Bond Cleavage

open access: yesAngewandte Chemie International Edition, Accepted Article.
Using a combination of metal‐promoted reactivity, in‐situ covalent bond modification, and hydrogen bonding‐promoted fluorine labilization, a unified approach was developed to self‐assemble a library of customizable ligand architectures directly at the nickel center via selective cleavage of C‒F or C‒O bonds and the formation of C‒C or C‒N bonds.
Aleksandr Sorvanov   +5 more
wiley   +1 more source

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