Well-defined alkylpalladium complexes with pyridine-carboxylate ligands as catalysts for the aerobic oxidation of alcohols [PDF]
Neophylpalladium complexes of the type [Pd(CH(2)CMe(2)Ph)(N-O)(L)], where N-O is picolinate or a related bidentate, monoanionic ligand (6-methylpyridine-2-carboxylate, quinoline-2-carboxylate, 2-pyridylacetate or pyridine-2-sulfonate) and L is pyridine ...
Cámpora Pérez, Juan +4 more
core +1 more source
The N‐Bromo‐Hammick Intermediate
Spectroscopic and computational analysis uncovers the σ2σ*0 electronic structure of the N‐bromo‐Hammick intermediate, a singlet N‐heterocyclic carbene isolated in solid neon, whose back‐isomerization to bromopyridine proceeds via a planar transition state.
Virinder Bhagat, J. Philipp Wagner
wiley +1 more source
Modulation of Amide Bond Rotamers in 5-Acyl-6,7-dihydrothieno[3,2-c]pyridines [PDF]
2-Substituted N-acyl-piperidine is a widespread and important structural motif, found in approximately 500 currently available structures, and present in nearly 30 pharmaceutically active compounds.
Lanyon-Hogg, T +5 more
core +3 more sources
Similarity Between the Action of Pteridines and Tryptophan Metabolites on Lipid Metabolism
Incorporation of fatty acids into phospholipids has been investigated using samples of rat liver tissue homogenate, Krebs-Ringer-phosphate buffer (pH=7.4) containing 0.3% albumin, fatty acid mixture and glycerol. The addition of anthranilic acid (2.2 and
Rudzite Vera +3 more
doaj +1 more source
Reasoned opinion on the modification of the existing MRL for aminopyralid in rape seed [PDF]
<p>In accordance with Article 6 of Regulation (EC) No 396/2005, France, herewith referred to as the evaluating Member State (EMS), received an application from Dow AgroSciences to modify the existing MRL(s) for the active substance aminopyralid in ...
European Food Safety Authority
doaj +1 more source
Green and Sustainable Chemistry Approaches on Azide‐Based Click Reactions in Polymer Science
Click Chemistry, particularly the azide‐alkyne cycloaddition (AAC) reaction, has revolutionized polymer chemistry, enabling precise and efficient synthesis of advanced functional materials. With its high regioselectivity, mild reaction conditions, and versatility, AAC reactions align closely with the principles of Green and Sustainable Chemistry.
Hatice Mutlu +3 more
wiley +1 more source
Biocatalytic conversion of lignin to aromatic dicarboxylic acids in Rhodococcus jostii RHA1 by re-routing aromatic degradation pathways [PDF]
The heteropolymer lignin represents an untapped resource for production of renewable aromatic chemicals, if efficient depolymerisation methods can be developed.
Bugg, Tim +4 more
core +1 more source
ChemInform Abstract: Electrochemical Synthesis of Nicotinic Acid from β‐Picoline.
Department of Chemistry, Kashmir University, Srinagar-190 006 Manuscript received 18 February 1988, revised 19 May 1988, accepted 8 June 1988 Electrosyathesis or nicotinic acid from -picoline by potentiostatic oxidation is reported. Efficencies of different electrodes are compared by considering changes in concentration of anolyte and substrate ...
P. N. Gupta, G. M. Rather
openaire +2 more sources
Enhancing Lipidomics With High‐Resolution Ion Mobility‐Mass Spectrometry
ABSTRACT Lipids, indispensable yet structurally intricate biomolecules, serve as critical regulators of cellular function and disease progression. Conventional lipidomics, constrained by limited resolution for isomeric and low‐abundance species, has been transformed by ion mobility‐mass spectrometry (IM‐MS).
Gaoyuan Lu +3 more
wiley +1 more source
Abstract Aims Metabolic dysfunction‐associated steatotic liver disease (MASLD) represents a major health burden in children and adolescents with obesity. This study aimed to characterize metabolic alterations associated with obesity‐related MASLD and to evaluate the potential of tryptophan (TRP)‐derived metabolites as non‐invasive biomarkers for early ...
Shumin Zhan +20 more
wiley +1 more source

