The N‐Bromo‐Hammick Intermediate
Chemistry – A European Journal, Volume 31, Issue 60, October 27, 2025.Spectroscopic and computational analysis uncovers the σ2σ*0 electronic structure of the N‐bromo‐Hammick intermediate, a singlet N‐heterocyclic carbene isolated in solid neon, whose back‐isomerization to bromopyridine proceeds via a planar transition state.
Virinder Bhagat, J. Philipp Wagner
wiley +1 more source
Charge Transfer-oxy Radical Mechanism for Anti-cancer Agents [PDF]
, 1986 The proposal is advanced that anti-cancer drugs generally function by charge transfer resulting in formation of toxic oxy radicals which destroy the neoplasm.
Ames, James R. +5 more
core +1 more source
MALDI-TOF mass spectrometry in textile industry [PDF]
, 2008 In this paper are presented the possibilities of using matrix assisted laser desorption ionization time of flight (MALDI-TOF) mass spectrometry in textile industry.
Dinca, Nicolae +2 more
core +1 more source
LMCT‐Driven Iron Photocatalysis: Mechanistic Insights and Synthetic Applications
Chemistry – A European Journal, Volume 31, Issue 58, October 16, 2025.LMCT‐driven iron photocatalysis: This review discusses recent developments in ligand‐to‐metal charge transfer (LMCT)‐driven iron photocatalysis, emphasizing mechanistic insights and diverse synthetic applications. By classifying Fe(III)–L bond homolysis pathways, it highlights iron's potential as a sustainable alternative to precious metals for radical‐
Amrita Chaudhuri +4 more
wiley +1 more source
Inhibiting tryptophan metabolism enhances interferon therapy in kidney cancer. [PDF]
, 2016 Renal cell carcinoma (RCC) is increasing in incidence, and a complete cure remains elusive. While immune-checkpoint antibodies are promising, interferon-based immunotherapy has been disappointing.
Abu Aboud, Omran +13 more
core +2 more sources
Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction [PDF]
, 2009 The addition of different carboxylic acids dianions to N-benzylidenebenzeneamine have been studied. The outcome of the reaction depends on the acid. Saturated ones lead to β-aminoacids with good yields and syn-selectivity whereas α,β-unsaturated ones ...
Gil Grau, Salvador +2 more
core +1 more source
Synthesis and structural characterization of 6-(N-Methyl-pyridin-2-ylcarbamoyl)-pyridine-2-carboxylic acid methyl ester isomers [PDF]
, 2017 A series of monoamide isomers have been successfully synthesised and characterised using combination of common spectroscopic techniques such Fourier Transform Infrared (FT-IR), 1H and 13C Nuclear Magnetic Resonance (NMR) and Ultraviolet-visible (UV-vis).
Maisara Abdul Kadir, +2 more
core +1 more source
Expression and Characterization of 3,6-Dihydroxy-picolinic Acid Decarboxylase PicC of Bordetella bronchiseptica RB50 [PDF]
, 2023 Cansheng Yuan +6 more
openalex +1 more source
Comparison of the Plasma Metabolome Profiles Between the Internal Thoracic Artery and Ascending Aorta in Patients Undergoing Coronary Artery Bypass Graft Surgery Using Gas Chromatography Time-of-Flight Mass Spectrometry. [PDF]
, 2019 BackgroundThe left internal thoracic artery (LITA) has been used as the first conduit of choice in coronary artery bypass grafting (CABG) because of excellent long-term patency and outcomes.
Cho, Joo Youn +6 more
core