Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction [PDF]
The addition of different carboxylic acids dianions to N-benzylidenebenzeneamine have been studied. The outcome of the reaction depends on the acid. Saturated ones lead to β-aminoacids with good yields and syn-selectivity whereas α,β-unsaturated ones ...
Gil Grau, Salvador +2 more
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Synthesis and structural characterization of 6-(N-Methyl-pyridin-2-ylcarbamoyl)-pyridine-2-carboxylic acid methyl ester isomers [PDF]
A series of monoamide isomers have been successfully synthesised and characterised using combination of common spectroscopic techniques such Fourier Transform Infrared (FT-IR), 1H and 13C Nuclear Magnetic Resonance (NMR) and Ultraviolet-visible (UV-vis).
Maisara Abdul Kadir, +2 more
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An investigation into the extracellular enzymes produced by Dothistroma pini and their relation to pathogenicity : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Biochemistry. [PDF]
The aim of this chapter is to provide a background against which the pathogenic action of Dothistroma pini can he discussed. Plant Diseases. There are three principal groups of organisms implicated as causal agents of diseases in planto; fungi, bacteria ...
Brunt, Peter John
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Picolinic acid promoted oxidative decarboxylation of phenylsulfinylacetic acid by Cr(VI)
The kinetics and mechanism of picolinic acid promoted reaction of phenylsulfinylacetic acid (PSAA) with Cr(VI) was carried out in aqueous acetonitrile medium under pseudo first order conditions. The reaction follows Michaelis-Menten type of kinetics with respect to PSAA.
P. Subramaniam, N. T. Selvi
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Complexes of Zinc With Picolinic and Aspartic Acids Inactivate Free Varicella-Zoster Virions
Zn(II) picolinate and aspartate, Zn(pic)2 and Zn(asp)2, have been shown to inhibit key steps of the replication of HSV-1. In the present study we describe the effect of Zn(pic)2 and Zn(asp)2 on the replication of VZV and on the infectivity of free ...
Stoyan Shishkov +4 more
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Redetermination of picolinic acid hydrochloride at 150 K
The structure of the title compound, C6H6NO2+·Cl−, was previously determined at ambient temperature [Laurent (1965). Acta Cryst. 18, 799–806]. This redetermination at 150 K is to a far higher precision. On cooling to 150 K, the unit cell contracts most in the π–π stacking direction, b, and rather less so in the directions involving the strongly ...
Mark R. J. Elsegood +2 more
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Comparative solution equilibrium studies on pentamethylcyclopentadienyl rhodium complexes of 2,2'-bipyridine and ethylenediamine and their interaction with human serum albumin [PDF]
Complex formation equilibri um processes of the (N,N) donor containing 2,2' - bipyridine (bpy) and ethylenediamine (en) with (η 5 - pentamethylcyclopentadienyl) rhodium(III) were investigated in aqueous solution via pH -
Dömötör, Orsolya +4 more
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Department of Chemistry, Jadavpur University, Kolkata-700 032, India Manuscript received 16 June 2000, revised 1 November 2000, accepted 2 February 2001 The kinetics and mechanism of the oxidation of sulfite to sulfate by tris(pyridine-2- carboxylato)manganese(III) in Na(pic) -picH (where, Na(pic) = sodium salt of picolinic acid, picH = picolinic acid)
Gupta, Kalyan Kali Sen +1 more
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Ruthenium versus platinum: interactions of anticancer metallodrugs with duplex oligonucleotides characterised by electrospray ionisation mass spectrometry [PDF]
The binding of the ruthenium-based anticancer drug candidates KP1019, NAMI-A and RAPTA-T towards different double-stranded oligonucleotides was probed by electrospray ionisation mass spectrometry and compared with that of the widely used platinum-based ...
Dyson, Paul +4 more
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