Results 211 to 220 of about 37,707 (289)

Heterometallic Coordination Compounds with Amino‐Acid Dithiocarbamate Ligands

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
This comprehensive review surveys the synthesis, molecular structures, and properties of heterobimetallic coordination compounds with amino‐acid dithiocarbamate ligands (AA‐DTCs), important O,S‐ditopic ligands. Most of the known compounds form infinite assemblies of different dimensions rather than molecular entities in the solid state.
Phil Köhler
wiley   +1 more source

Exploring Bioinspired Ln3+ Complexes for Cu2+ Detection: Design and Efficacy as MRI Contrast Agents

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Gd3+ complexes bearing a bioinspired Cu2+‐binding site derived from ATCUN are studied as MRI contrast agents. The presence of two amino acids (GH) is necessary to bind Cu2+ and trigger a relaxivity increase. This is due to a higher number of H2O retained close to Gd3+ through H‐bonding with Cu2+. Remarkably, the system remains selective for Cu2+ vs Zn2+
Martina Sanadar   +7 more
wiley   +1 more source

Recent Developments for the Ring Opening of Pyrrolidines and Unstrained Cyclic Amines via C−N Bond Cleavage

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights recent advancements in the deconstructive transformation of unstrained cyclic amines, with a particular focus on the C−N bond cleavage of pyrrolidines. Various methodologies, including von Braun‐type, oxidative, and reductive approaches, facilitate the synthesis of diverse amines and the expansion of chemical space.
Eisuke Ota, Junichiro Yamaguchi
wiley   +1 more source

A Novel Reductive Amino Cyclization Method and Its Application for the Syntheses of Pyrrolidine and Piperidine Nucleus

open access: gold, 1986
Masanori Somei   +4 more
openalex   +1 more source

Synthesis and Reactivity of 1,4‐Ethano‐1,5‐Naphthyridine Derivatives Using Microwave Activation or Flow Chemistry

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The design of original disubstituted 3,4‐dihydro‐2H‐1,4‐ethano‐1,5‐naphthyridine derivatives is reported under classical and flow methodologies. The conditions are optimized and a wide range of boronic acids are used to determine the scope and limitations of Suzuki–Miyaura or Chan–Lam reactions. The design of some novel disubstituted 3,4‐dihydro‐2H‐1,4‐
Mazarine Laurent   +4 more
wiley   +1 more source

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