Results 51 to 60 of about 40,506 (345)

Supramolecular Chemistry in Metal–Organic Framework Materials

Advanced Materials, EarlyView.
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ, Georgia R. F. Orton, Danielle E. Schier, Neil R. Champness   +3 more
wiley   +1 more source

Enantioselective Synthesis of α-(Hetero)aryl Piperidines through Asymmetric Hydrogenation of Pyridinium Salts and Its Mechanistic Insights.

Organic Letters, 2018
Enantioselective synthesis of α-aryl and α-heteroaryl piperidines is reported. The key step is an iridium-catalyzed asymmetric hydrogenation of substituted N-benzylpyridinium salts.
Bo Qu, Hari P R Mangunuru, Sergei Tcyrulnikov, Daniel Rivalti, O. Zatolochnaya, Dmitry Kurouski, Suttipol Radomkit, Soumik Biswas, Shuklendu D Karyakarte, K. Fandrick, J. Sieber, S. Rodriguez, J. Desrosiers, N. Haddad, K. McKellop, S. Pennino, Heewon Lee, N. Yee, Jinhua J. Song, Marisa C. Kozlowski, C. Senanayake   +20 more
semanticscholar   +1 more source

Electrochemical Cell Designs for Efficient Carbon Dioxide Reduction and Water Electrolysis: Status and Perspectives

Advanced Materials, EarlyView.
This review discusses recent innovations in electrochemical CO2 reduction reactions (eCO2RR) and hydrogen evolution reaction cell designs. The latest advancements in in situ cells for operando characterization are also presented. Optimizations in flow patterns, membrane electrode assemblies, electrolyte engineering, and counter‐anodic reactions provide
Zhangsen Chen, Lei Zhang, Shuhui Sun, Gaixia Zhang   +3 more
wiley   +1 more source

PEG-embedded KBr3: A recyclable catalyst for multicomponent coupling reaction for the efficient synthesis of functionalized piperidines

Beilstein Journal of Organic Chemistry, 2011
PEG-embedded potassium tribromide ([K+PEG]Br3−) was found to be an efficient and recyclable catalyst for the synthesis of functionalized piperidines in high yields in a one step, three component coupling between aldehyde, amine and β-keto ester.
Sanny Verma, Suman L. Jain, Bir Sain
doaj   +1 more source

Rational Development of a Novel Emulgel Adjuvant for Single‐Shot Effective Vaccination: A Multivariate Analysis Approach

Advanced Materials, EarlyView.
Using multivariate analysis, a novel emulgel adjuvant is developed by combining key nanoemulsion formulation variables–hydrogel trapping, small globule size, and mannide monooleate surfactant–achieving 10× greater immunogenicity than MF59 in mice after a single shot.
Ahmed O. Shalash, Waleed M. Hussein, Ummey J. Nahar, Jingwen Wang, Lantian Lu, Armira Azuar, Jolynn J. E. Kiong, Prashamsa Koirala, Zeinab G. Khalil, Istvan Toth   +9 more
wiley   +1 more source

Gold(I)-Catalyzed Enantioselective Annulations between Allenes and Alkene-Tethered Oxime Ethers: A Straight Entry to Highly Substituted Piperidines and aza-Bridged Medium-Sized Carbocycles.

Journal of the American Chemical Society, 2018
Piperidine scaffolds are present in a wide range of bioactive natural products and are therefore considered as highly valuable, privileged synthetic targets.
David C Marcote, Iván Varela, J. Fernández-Casado, J. Mascareñas, F. López   +4 more
semanticscholar   +1 more source

Fused bicyclic piperidines and dihydropyridines by dearomatising cyclisation of the enolates of nicotinyl-substituted esters and ketones

Beilstein Journal of Organic Chemistry, 2010
The silyl enol ether derivatives of ketones or esters tethered by a hydrocarbon or ether linkage to the 3-position of a pyridine ring undergo dearomatising nucleophilic attack on the ring once it is activated (as an acylpyridinium species) by the ...
Heloise Brice, Jonathan Clayden, Stuart D. Hamilton   +2 more
doaj   +1 more source

HMPA-Catalyzed Transfer Hydrogenation of 3-Carbonyl Pyridines and Other N-Heteroarenes with Trichlorosilane

Molecules, 2019
A method for the HMPA (hexamethylphosphoric triamide)-catalyzed metal-free transfer hydrogenation of pyridines has been developed. The functional group tolerance of the existing reaction conditions provides easy access to various piperidines with ester ...
Yun Fu, Jian Sun
doaj   +1 more source

Silacyclohexanes, Sila(hetero)cyclohexanes and Related Compounds: Structure and Conformational Analysis

Molecules, 2020
Conformational analysis of Si-mono- and Si,Si-disubstituted silacyclohexanes as well as their analogues with a heteroatom(s) in the ring is reviewed with the focus on the recent results.
Bagrat A. Shainyan
doaj   +1 more source

Efficient Synthesis of Amino Lactones via Copper‐catalysed Alkene Aminooxygenation

Advanced Synthesis &Catalysis, EarlyView.
Abstract The synthesis of 5–7 membered oxygenated heterocycles by intramolecular aminooxygenation of unsaturated alkenes using commercially available N‐fluorobenzenesulfonimide as amination reagent and TpiPr2Cu(NCCH3) as precatalyst is reported. With unsaturated aliphatic carboxylic acids, the corresponding lactones are obtained from moderate to almost
Martina Casciotti, José M. Muñoz‐Molina, Tomás R. Belderrain, Pedro J. Pérez   +3 more
wiley   +1 more source