Enantiomeric separation of organophosphorus pesticides by capillary electrophoresis. Application to the determination of malathion in water samples after preconcentration by off-line solid-phase extraction [PDF]
The separation of the enantiomers of a group of organophosphorus pesticides (OPs) has been investigated by electrokinetic chromatography (EKC) using different anionic cyclodextrins as chiral selectors. The use of a 25 mM Tris buffer (pH 7.0), 20 mM in CM-
Blanco, Elisa +5 more
core +2 more sources
The design of the mobile phase additive useful in HPLC analysis on two types of chiral stationary phases, one based on chiral crown ether, and another based on polysaccharide derivative, was developed. CROWNPAK® CR-I, the chiral stationary phase bearing (
Tohru Shibata +5 more
doaj +1 more source
Core-Shell Columns in High-Performance Liquid Chromatography: Food Analysis Applications [PDF]
Theincreased separation efficiency provided by the newtechnology of column packed with core-shell particles in high-performance liquid chromatography (HPLC) has resulted in their widespread diffusion in several analytical fields: from pharmaceutical ...
Preti, Raffaella
core +3 more sources
Achiral and chiral molecular descriptors were used to build models that predict the global retention of chiral molecules on the one hand, and their enantioselectivity, separation and elution sequence on the other.
Pieter De Gauquier +6 more
doaj +1 more source
Enzymatic and chromatographic resolution procedures applied to the synthesis of the phosphoproline enantiomers [PDF]
Financial support to this work was provided by Ministerio de Economía y Competitividad–FEDER (grants CTQ2011-24237,CTQ2013-44153-P, and CTQ2013-40855 ...
Arizpe, Alicia +7 more
core +2 more sources
Advancements in Mass Spectrometry‐Based Glycomics in Food and Nutritional Science
ABSTRACT This review highlights advancements in mass spectrometry (MS)‐based glycomics in food and nutritional science. Carbohydrates, which are vital for human health, exhibit complex structures, making their analysis challenging. MS has become an indispensable tool for elucidating the structures of carbohydrates, including glycans, through soft ...
JaeHui Song +3 more
wiley +1 more source
Characterization of exopolysaccharides produced by seven biofilm-forming cyanobacterial strains for biotechnological applications [PDF]
The molecular identification of seven biofilmforming cyanobacteria and the characterization of their exopolysaccharides were made and considered in terms of potential biotechnological applications.
Bruno, L +6 more
core +1 more source
Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals
Chiral (R‐MBA)2SnBr6 and (S‐MBA)2SnBr6 metal halides crystallize in enantiomorphic helical space groups P61 and P65, respectively. The helical orientation of chiral molecules in the lattice arises due to strong N─H···Br and C─H···π interactions and is visualized via sixfold symmetry.
Ramavath Babu +13 more
wiley +2 more sources
Sample Preparation and Separation of Lignans by Liquid Chromatography
ABSTRACT Lignans are important phytochemicals found mostly in the resins of coniferous trees, but are also introduced into human diets through foods such as sesame seeds and extra‐virgin olive oil. They are pharmacologically interesting mainly because of their antioxidant activities, and they have also been shown to have cytotoxic and antimicrobial ...
Miikka Paloluoto, Susanne K. Wiedmer
wiley +1 more source
Chiral metabolites of ketamine exerting rapid-onset yet sustained antidepressant effects may be marketed directly in the future, but require chemo- and enantio-selective chromatographic methods for quality assurance and control.
Robert K. Hofstetter +5 more
doaj +1 more source

