Results 91 to 100 of about 545 (146)

Additive Pummerer rearrangements. Asymmetric synthesis of (–)-methyl jasmonate

open access: closedJ. Chem. Soc., Chem. Commun., 1985
Examples of mild, additive Pummerer rearrangements are given; one example involves asymmetric carbon–carbon bond formation as the key step for synthesis of (–)-methyl jasmonate.
Gary H. Posner   +2 more
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Pummerer rearrangements using chlorotrimethylsilane

Journal of the Chemical Society, Perkin Transactions 1, 1984
Attempted Pummerer rearrangement of 3-methoxycarbonylthian-4-one S-oxide in refluxing acetic anhydride gives unexpected products in which β-carbon oxidation and ring contraction has taken place. Treatment of 3-methoxycarbonylthian-4-one with N-chlorosuccinimide gives similar rearrangement products.
Simon Lane   +2 more
openaire   +1 more source

ChemInform Abstract: Pummerer Rearrangements Using Chlorotrimethylsilane.

Chemischer Informationsdienst, 1984
Abstract3‐Carbomethoxy‐thian‐4‐on‐S‐oxid wird mit Trimethylchlorsilan je nach Reaktionsbedingungen zu unterschiedlich zusammengesetzten Gemischen der als‐ungesättigten Sulfide (II) und (III) sowie der Chlorierungsprodukte (IV) und (V) umgesetzt (Tabelle).
S. LANE, S. J. QUICK, R. J. K. TAYLOR
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Pummerer-Type Rearrangement of α-Chloroalkyl Sulfoxides

open access: closed, 2007
J. Drabowicz   +2 more
openaire   +2 more sources

Highly Stereoselective Vinylogous Pummerer Rearrangement

Phosphorus, Sulfur, and Silicon and the Related Elements, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Jose L. Garcia Ruano   +4 more
openaire   +1 more source

PUMMERER REARRANGEMENT OF ETHYL METHYLSULFINYLTHIOACETATE

Phosphorus, Sulfur, and Silicon and the Related Elements, 1990
Abstract Ethyl methylsulfinylthioacetate undergoes Pummerer rearrangement with thionyl chloride, trifluoroacetic anhydride or with acetic anhydride-trifluoroacetic anhydride mixture, but not with acetic anhydride alone. These reactivities are compared to those for methyl methylsulfinylacetate and ω-methylsulfinylacetophenone and interpreted in terms of
B. Wladislaw, L. Marzorati, J. Gruber
openaire   +1 more source

Fluoro-Pummerer rearrangement and analogous reactions

Journal of Fluorine Chemistry, 2012
Abstract Fluorine containing compounds hold huge promise for pharmaceuticals and agrochemicals due to their specific therapeutic potency or pesticide properties. Therefore, the development of selective and efficient methods for the introduction of fluorine or fluorinated groups into organic molecules is one of the most important tasks in ...
Verena Hugenberg, Günter Haufe
openaire   +2 more sources

ChemInform Abstract: Intramolecular Capture of Pummerer Rearrangement Intermediates. Part 3. Interrupted Pummerer Rearrangement: Capture of Tricoordinate Sulfur Species Generated Under Pummerer Rearrangement Conditions.

ChemInform, 1992
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
D. K. BATES, R. T. WINTERS, J. A. PICARD
openaire   +1 more source

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