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Additive Pummerer rearrangements. Asymmetric synthesis of (–)-methyl jasmonate
Examples of mild, additive Pummerer rearrangements are given; one example involves asymmetric carbon–carbon bond formation as the key step for synthesis of (–)-methyl jasmonate.
Gary H. Posner +2 more
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Pummerer rearrangements using chlorotrimethylsilane
Journal of the Chemical Society, Perkin Transactions 1, 1984Attempted Pummerer rearrangement of 3-methoxycarbonylthian-4-one S-oxide in refluxing acetic anhydride gives unexpected products in which β-carbon oxidation and ring contraction has taken place. Treatment of 3-methoxycarbonylthian-4-one with N-chlorosuccinimide gives similar rearrangement products.
Simon Lane +2 more
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ChemInform Abstract: Pummerer Rearrangements Using Chlorotrimethylsilane.
Chemischer Informationsdienst, 1984Abstract3‐Carbomethoxy‐thian‐4‐on‐S‐oxid wird mit Trimethylchlorsilan je nach Reaktionsbedingungen zu unterschiedlich zusammengesetzten Gemischen der als‐ungesättigten Sulfide (II) und (III) sowie der Chlorierungsprodukte (IV) und (V) umgesetzt (Tabelle).
S. LANE, S. J. QUICK, R. J. K. TAYLOR
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Pummerer-Type Rearrangement of α-Chloroalkyl Sulfoxides
J. Drabowicz +2 more
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Highly Stereoselective Vinylogous Pummerer Rearrangement
Phosphorus, Sulfur, and Silicon and the Related Elements, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
Jose L. Garcia Ruano +4 more
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PUMMERER REARRANGEMENT OF ETHYL METHYLSULFINYLTHIOACETATE
Phosphorus, Sulfur, and Silicon and the Related Elements, 1990Abstract Ethyl methylsulfinylthioacetate undergoes Pummerer rearrangement with thionyl chloride, trifluoroacetic anhydride or with acetic anhydride-trifluoroacetic anhydride mixture, but not with acetic anhydride alone. These reactivities are compared to those for methyl methylsulfinylacetate and ω-methylsulfinylacetophenone and interpreted in terms of
B. Wladislaw, L. Marzorati, J. Gruber
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Fluoro-Pummerer rearrangement and analogous reactions
Journal of Fluorine Chemistry, 2012Abstract Fluorine containing compounds hold huge promise for pharmaceuticals and agrochemicals due to their specific therapeutic potency or pesticide properties. Therefore, the development of selective and efficient methods for the introduction of fluorine or fluorinated groups into organic molecules is one of the most important tasks in ...
Verena Hugenberg, Günter Haufe
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ChemInform, 1992
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
D. K. BATES, R. T. WINTERS, J. A. PICARD
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
D. K. BATES, R. T. WINTERS, J. A. PICARD
openaire +1 more source

