Results 21 to 30 of about 545 (146)
Applications of N─F─Based Reagents in the Synthesis of Organochalcogen Compounds
Herein, we provide a comprehensive review of recent advances in synthetic strategies to access organochalcogen‐decorated compounds using N─F reagents as efficient oxidants for converting chalcogen–chalcogen bonds into electrophilic chalcogen‐based species.
Thiago Anjos +5 more
wiley +1 more source
Recent Advances in Stereospecific Transformations of Organoboron Reagents
Enantioenriched boronic esters when activated with organolithiums, can be transformed into boronate complexes that act as chiral organometallic‐type nucleophiles and can engage a wide variety of electrophiles in stereospecific cross‐coupling reactions.
Shubham Ojha +3 more
wiley +1 more source
Chemistry, Applications, and Synthesis Methods of Indole Derivatives: A Comprehensive Review
Indole and its derivatives represent a vital class of heterocycles with broad applications in pharmaceuticals, agrochemicals, and materials science. This review explores their applications, biosynthesis, key derivatives such as tryptophan, and presents an overview of both classical and modern synthetic methodologies, with a focus on sustainable ...
Raphael Silva Moratório de Moraes +10 more
wiley +1 more source
The inclusion of a tetrahydrothiopheno equatorial substituent on a glycoluril moiety of a cucurbit[n]uril provides an avenue to reactive derivatization. This process extends the potential for future applications of the cucurbituril homologues 7 and 8.
Ahmed Abdulrahman +5 more
wiley +1 more source
The combination of three privileged structures, fullerenes, selenosugars, and steroids, has led to new hybrids in which the novel methanofullerenes are decorated with fragments of biological interest. Theoretical calculations at the DFT‐B3LYP‐D3(BJ)/6‐311G(2d,p) level allowed the determination of the most stable conformation, and docking simulations ...
Reinier Lemos +5 more
wiley +1 more source
Hemiindigoids as Prominent Photoswitch Scaffolds
This review explores the synthesis, photophysical properties, and diverse applications of hemiindigoid photoswitches, a class of chromophores derived from indigo. With unique visible‐light responsiveness, high thermal bistability, and rapid, reversible switching, hemiindigoids present promising advances in photopharmacology, molecular solar thermal ...
Aurélie Gernet +4 more
wiley +1 more source
Mono‐ADP‐Ribosylation of Peptides: An Overview of Synthetic and Chemoenzymatic Methodologies
Adenosine diphosphate (ADP)‐ribosylation is a post‐translational modification that regulates key biological processes. It occurs on a wide range of amino acids, including arginine, cysteine, serine, and glutamic acid. Well‐defined ADP‐ribosylated peptides are valuable tools for investigating the structures, mechanisms of action, and interaction ...
Hugo Minnee +2 more
wiley +1 more source
Recent Applications of Sulfonium Salts in Synthesis and Catalysis
This review summarizes the recent developments on the synthetic applications of sulfonium salts with an emphasis on the description of the operating mechanistic pathways. Abstract The use of sulfonium salts in organic synthesis has experienced a dramatic increase during the last years that can arguably be attributed to three main factors; the ...
Sven Timmann, Zeyu Feng, Manuel Alcarazo
wiley +1 more source
This review illustrates chemical aspects and molecular‐level chemistry behind distinctive functions of the cyclophane‐based functional materials with a particular focus on through‐space conjugated π‐stacked molecules and polymers for application in organic emitters, arylenevinylene polymers developed by ROMP approach, and structurally‐controlled ...
Zahid Hassan
wiley +1 more source

