Results 111 to 120 of about 3,742 (239)
Contribution of NMR spectroscopy to the mechanistic understanding of photochromism
Along with classical UV-Visible spectroscopy allowing for the determination of intrinsic properties (λmax,ε), multinuclear NMR spectroscopy is a promising and useful tool for studying photochromic reactions.
S. Delbaere +3 more
doaj +1 more source
In aged rats, 6‐month SXZ treatment reversed spatial memory deficits and preserved hippocampal integrity. Mechanistic assays show that SXZ promotes glutathione metabolism and inhibits ferroptosis via p53/SLC7A11/GPX4 and Keap1/Nrf2/HO‐1 pathways. SXZ is a novel neuroprotective agent against age‐related cognitive decline.
Mengya Liu +6 more
wiley +1 more source
We investigated the vibrational dynamics of 4‐(dicyano‐methylen)‐2‐methyl‐6‐(4‐dimethylaminostyryl)‐4H‐pyran (DCM) upon one‐photon excitation (1PE) at 515 nm and upon two‐photon excitation (2PE) at 1030 nm in the spectral range of the nitrile vibrations. Vibrational dynamics of the two nitrile vibrations are traced in real‐time up to 7 ns.
Mathias Hartmann +6 more
wiley +1 more source
Hydroxyl-assisted oxidative annulations of alkynes were accomplished with an inexpensive ruthenium(II) complex, delivering fluorescent pyrans via highly site selective as well as chemo- and regioselective C-H/O-H bond functionalizations.Alexander von ...
Ackermann, Lutz +2 more
core +1 more source
An endophytic fungus (Daldinia sp.) was isolated from the leaves of Avicennia officinalis collected from mangrove forests of Goa. The ethyl acetate extract of Avicennia officinalis (AO‐EA) of the identified endophyte demonstrated antibacterial and antibiofilm activity against Escherichia coli and Shigella sp.
Nickita Dutta +3 more
wiley +1 more source
ABSTRACT Anthocyanins are plant derived biomolecules that play roles in pollination and protection against ultraviolet light (UV) radiation, as well as reactive oxygen and nitrogen species (ROS and RNS, respectively). Cyanidin 3‐O‐glucoside (C3G), a common anthocyanin in the diet, exhibits antioxidant capacity that depends on its chemical structure ...
Eiko Osawa‐Martínez +6 more
wiley +1 more source
A modular UDP‐glycosyltransferase and cytochrome P450 system for soyasaponin C‐22 modification
SUMMARY Soybean (Glycine max (L.) Merr.) produces triterpenoid saponins, called soyasaponins, which are categorised as 2,3‐dihydro‐2,5‐dihydroxy‐6‐methyl‐4H‐pyran‐4‐one (DDMP) saponins and group A saponins based on the chemical modifications at the C‐22 position of their triterpene skeleton.
Susumu Hiraga +13 more
wiley +1 more source
Abstract The conclusions of the European Food Safety Authority (EFSA) following the peer review of the initial risk assessments carried out by the competent authorities of the rapporteur Member State, Sweden, and co‐rapporteur Member State, Netherlands, for the pesticide active substance Trichoderma afroharzianum (formerly harzianum) T‐22 are reported.
European Food Safety Authority (EFSA) +47 more
wiley +1 more source
Elastic and electronically inelastic scattering of electrons by 2H-pyran and 4H-pyran molecules
We report on elastic and electronically inelastic integral and differential cross sections for electron collisions with the 2H-pyran and 4H-pyran molecules. The scattering calculations were performed with the Schwinger multichannel method and aimed to (i) investigate the formation of resonant states, (ii) assign and compare the resonance spectrum of ...
Murilo O. Silva +3 more
openaire +1 more source
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill +5 more
wiley +1 more source

