Results 101 to 110 of about 3,431 (233)
A stereodivergent synthesis of enantiopure 3,6-dihydro-2H-pyrans is presented. The addition of lithiated enol ethers to carbohydrate-derived nitrones afforded syn- or anti-configured hydroxylamine derivatives 4a–d that were cyclized under Lewis acidic ...
Fabian Pfrengle, Hans-Ulrich Reissig
doaj +1 more source
Photochromic carbazole photoinitiators for precision visible‐light photopolymerization
New carbazole–naphthopyran derivatives were employed as visible‐light‐activated photoinitiators, enabling rapid and localized radical photopolymerization to produce well‐defined thin solid objects within minutes. Abstract Two carbazole derivatives, each incorporating a naphthopyran unit and an aromatic ketone, were synthesized and evaluated as ...
Mauro Magalhães +3 more
wiley +1 more source
Enantioselective synthesis of mono- and disubstituted 3,6-dihydro-2H-pyrans and 5, 6-dihydro pyran-2-ones. [PDF]
An enantioselective synthesis of mono- and disubstituted 3,6-dihydro-2H-pyrans and 5,6-dihydropyran-2-ones was achieved via ring-closing olefin metathesis, employing Grubb's catalyst, and starting from ready available chiral building ...
IZZO, Irene +10 more
core +2 more sources
This work demonstrates high‐performance solution‐processed NIR OPDs using DTP‐ and DTTP‐based NFAs (OC and SC), where donor‐core engineering enables tunable absorption and balanced optoelectronic properties; notably, DTP‐based devices achieve broad NIR response, low dark current, and high detectivity, highlighting their potential for advanced NIR ...
Jong‐Woon Ha +11 more
wiley +1 more source
Stimulation of Antibody Formation by Pyran Copolymer
SummaryPyran copolymer, administered with sheep red blood cells to mice, enhances the early rate of appearance of antibody-forming spleen cells. Although the cytotoxicity and pyrogenicity of pyran and bacterial endotoxins are similar, pyran, in contrast to endotoxin, does not trigger a nonspecific initiation of antibody formation; it only enhances ...
W, Braun +3 more
openaire +2 more sources
Resilience of floral scent emission after florivory
Florivory is thought to affect floral traits, impacting pollination. However, our data suggest a stability in post‐florivory scent emission, which may guarantee the maintenance of pollinator visitation regardless of florivory, indicating a resilience of natural systems with multiple and simultaneous interactions. Created in BioRender. Tunes, P.
P. Tunes +4 more
wiley +1 more source
Novel routes for the preparation of 2-amino-4H-pyran-3-carbonitrile 9, amino-arylbenzoic acid ester derivatives 13a,b, 2-aminotetrahydro-4H-chromene-3-carbonitrile 18, 3-amino-4-cyanotetrahydronaphthalene-2-carboxylic acid ester 26 and 4-amino-3,5 ...
Moustafa Sherief Moustafa +4 more
doaj +1 more source
Reference Data 1H and 13C NMR chemical shift assignment of some 3H-naphtho [ 2,1-b ] pyrans [PDF]
International audienceThe 1H and 13C NMR resonances of four 3H-naphtho[2,1-b]pyrans were completely and unambiguously assigned by a combination of homonuclear (gs-COSY), 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gs-HMBC) gradient ...
Campredon, Mylene, ` +5 more
core +1 more source
Stereoselective Synthesis of Pyrans from Epoxyalkenes: Dual Catalysis with Palladium and Brønsted Acid [PDF]
We describe regio- and stereoselective cycloisomerizations of alcohols tethered to epoxyalkenes, to construct alkene-substituted pyrans. These transformations are best catalyzed by Pd(PPh3)4 in the presence of phosphite ligands, and with ...
Noah A. Setterholm (5310182) +1 more
core +1 more source
5-Ureido-3,3-diphenyl-3H-naphtho[2,1-b]pyrans: Photoswitchable self-assembling architectures
5-Ureido-3,3-diphenyl-3H-naphtho[2,1-b]pyrans have been synthesized and their photochromic properties have been quantified using UV-Visible spectroscopy.
X. Sallenave +4 more
doaj +1 more source

