Results 101 to 110 of about 3,431 (233)

Addition of lithiated enol ethers to nitrones and subsequent Lewis acid induced cyclizations to enantiopure 3,6-dihydro-2H-pyrans – an approach to carbohydrate mimetics

open access: yesBeilstein Journal of Organic Chemistry, 2010
A stereodivergent synthesis of enantiopure 3,6-dihydro-2H-pyrans is presented. The addition of lithiated enol ethers to carbohydrate-derived nitrones afforded syn- or anti-configured hydroxylamine derivatives 4a–d that were cyclized under Lewis acidic ...
Fabian Pfrengle, Hans-Ulrich Reissig
doaj   +1 more source

Photochromic carbazole photoinitiators for precision visible‐light photopolymerization

open access: yesPolymer International, Volume 75, Issue 8, Page 722-728, August 2026.
New carbazole–naphthopyran derivatives were employed as visible‐light‐activated photoinitiators, enabling rapid and localized radical photopolymerization to produce well‐defined thin solid objects within minutes. Abstract Two carbazole derivatives, each incorporating a naphthopyran unit and an aromatic ketone, were synthesized and evaluated as ...
Mauro Magalhães   +3 more
wiley   +1 more source

Enantioselective synthesis of mono- and disubstituted 3,6-dihydro-2H-pyrans and 5, 6-dihydro pyran-2-ones. [PDF]

open access: yes, 2003
An enantioselective synthesis of mono- and disubstituted 3,6-dihydro-2H-pyrans and 5,6-dihydropyran-2-ones was achieved via ring-closing olefin metathesis, employing Grubb's catalyst, and starting from ready available chiral building ...
IZZO, Irene   +10 more
core   +2 more sources

Structure‐Controlled Cyclopentadithiophene Derived Non‐Fullerene Acceptors for Efficient Near‐Infrared Organic Photodetectors

open access: yesSmall, Volume 22, Issue 43, 3 August 2026.
This work demonstrates high‐performance solution‐processed NIR OPDs using DTP‐ and DTTP‐based NFAs (OC and SC), where donor‐core engineering enables tunable absorption and balanced optoelectronic properties; notably, DTP‐based devices achieve broad NIR response, low dark current, and high detectivity, highlighting their potential for advanced NIR ...
Jong‐Woon Ha   +11 more
wiley   +1 more source

Stimulation of Antibody Formation by Pyran Copolymer

open access: yesExperimental Biology and Medicine, 1970
SummaryPyran copolymer, administered with sheep red blood cells to mice, enhances the early rate of appearance of antibody-forming spleen cells. Although the cytotoxicity and pyrogenicity of pyran and bacterial endotoxins are similar, pyran, in contrast to endotoxin, does not trigger a nonspecific initiation of antibody formation; it only enhances ...
W, Braun   +3 more
openaire   +2 more sources

Resilience of floral scent emission after florivory

open access: yesPlant Biology, Volume 28, Issue 5, Page 1491-1506, August 2026.
Florivory is thought to affect floral traits, impacting pollination. However, our data suggest a stability in post‐florivory scent emission, which may guarantee the maintenance of pollinator visitation regardless of florivory, indicating a resilience of natural systems with multiple and simultaneous interactions. Created in BioRender. Tunes, P.
P. Tunes   +4 more
wiley   +1 more source

Organobase-catalyzed three-component reactions for the synthesis of 4H-2-aminopyrans, condensed pyrans and polysubstituted benzenes

open access: yesBeilstein Journal of Organic Chemistry, 2014
Novel routes for the preparation of 2-amino-4H-pyran-3-carbonitrile 9, amino-arylbenzoic acid ester derivatives 13a,b, 2-aminotetrahydro-4H-chromene-3-carbonitrile 18, 3-amino-4-cyanotetrahydronaphthalene-2-carboxylic acid ester 26 and 4-amino-3,5 ...
Moustafa Sherief Moustafa   +4 more
doaj   +1 more source

Reference Data 1H and 13C NMR chemical shift assignment of some 3H-naphtho [ 2,1-b ] pyrans [PDF]

open access: yes, 1999
International audienceThe 1H and 13C NMR resonances of four 3H-naphtho[2,1-b]pyrans were completely and unambiguously assigned by a combination of homonuclear (gs-COSY), 1H-detected heteronuclear one-bond (gs-HMQC) and long-range (gs-HMBC) gradient ...
Campredon, Mylene, `   +5 more
core   +1 more source

Stereoselective Synthesis of Pyrans from Epoxyalkenes: Dual Catalysis with Palladium and Brønsted Acid [PDF]

open access: yes, 2018
We describe regio- and stereoselective cycloisomerizations of alcohols tethered to epoxyalkenes, to construct alkene-substituted pyrans. These transformations are best catalyzed by Pd­(PPh3)4 in the presence of phosphite ligands, and with ...
Noah A. Setterholm (5310182)   +1 more
core   +1 more source

5-Ureido-3,3-diphenyl-3H-naphtho[2,1-b]pyrans: Photoswitchable self-assembling architectures

open access: yesInternational Journal of Photoenergy, 2004
5-Ureido-3,3-diphenyl-3H-naphtho[2,1-b]pyrans have been synthesized and their photochromic properties have been quantified using UV-Visible spectroscopy.
X. Sallenave   +4 more
doaj   +1 more source

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