Results 81 to 90 of about 3,431 (233)

Fluorescent Diarylethenes With Polar Groups: Synthesis, Spectra, and Optical Microscopy Applications

open access: yesChemistry – A European Journal, Volume 32, Issue 30, 13 August 2026.
Blinking green and flashing red: photo‐switchable and photo‐activatable probes emitting green and red light were prepared and applied as bioconjugates in super‐resolution optical microscopy. ABSTRACT The use of photoactivatable fluorescent diarylethenes (fDAEs) in biology‐related light microscopy has been restricted by the lack of probes having freely ...
Kakishi Uno   +6 more
wiley   +1 more source

Synthesis of the Core Tetracycle of the Spirobiflavonoid Daphnodorin C

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 30, 12 August 2026.
Core spirotetracycle of daphnodorin C: Oxidative ring contraction of benzofuro[3,2‐b]chromenones affords novel 2,3′‐spirobi[benzofuran]diones, rather than the isomeric spiroketals. The first synthesis of the spirobi[benzofuran]dione core structure of the spirobiflavonoid daphnodorin C is described.
Lukas Heemann   +2 more
wiley   +1 more source

An Efficient, Simple and Green Zn(Phen)2Cl2 Complex Catalyzed Synthesis of 4-H-Benzo[b]pyrans in Water at Ambient Temperature

open access: yesE-Journal of Chemistry, 2011
An efficient method for the synthesis of 4-H-benzo[b]pyrans has been developed by the use of Zn(Phen)2Cl2(2 mol%) as an ecofriendly catalyst. The mixture of an appropriate aldehyde, malononitrile and dimedone in the presence of the Zn(Phen)2Cl2 as an ...
E. Mosaddegh   +2 more
doaj   +1 more source

The Synthesis Use of a Difluorinated Amino‐Benzo‐Cinnoline Dyes (ABCDyes) Enables Fine Tuning of Emission Through Double SNAr Late‐Stage Functionalization

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 29, 7 August 2026.
An efficient synthesis of difluorinated amino‐benzo‐cinnoline dyes (ABCDyes) is reported. Their use for the late‐stage introduction of internal dinucleophilic species through a double SNAr reaction enables straightforward access to previously unexplored ABCDye analogs displaying tunable emission ranging from green to red.
Mélina Fabe   +3 more
wiley   +1 more source

Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles

open access: yesBeilstein Journal of Organic Chemistry, 2010
The Prins reaction was investigated using BF3·OEt2 as a Lewis acid. It has been recently demonstrated, that if BF3·OEt2 is used in stoichiometric amounts then these reactions generate fluorinated products where the BF3·OEt2 contributes fluoride ion to ...
Guillaume G. Launay   +2 more
doaj   +1 more source

Chemoenzymatic Synthesis of Chiral Piperidines Using the Immobilized Transaminase ATA‐117 in Continuous Flow Reactors

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 15, 1 August 2026.
A robust continuous flow chemoenzymatic process was developed for the stereoselective synthesis of cis‐(2R,6R)‐2,6‐disubstituted piperidines, including the natural alkaloid (–)‐pinidinone. The asymmetric transamination of α,β‐unsaturated ketones was catalyzed by immobilized ATA‐117, followed by spontaneous aza‐Michael cyclization, providing the desired
Sara Vicinanza   +11 more
wiley   +1 more source

The intramolecular capture of thermally generated merocyanine dyes derived from naphthopyrans: Photochromism of 5-(diarylhydroxymethyl)-2H-naphtho[1,2-b]pyrans [PDF]

open access: yes, 2012
A series of 2H-naphtho[1,2-b]pyrans bearing a diarylmethanol unit at C-5 have been synthesised by the addition of an excess of an aryllithium reagent to alkyl 2H-naphtho[1,2-b]pyran-5-carboxylate precursors.
Kolla, Suresh B.   +7 more
core   +1 more source

In Vitro Antidiabetic Evaluation and Phytochemical Characterization of Sapindus mukorossi Fruit Pericarp Extract

open access: yesApplied Research, Volume 5, Issue 4, August 2026.
Sapindus mukorossi fruit pericarp is a promising source of polar polyphenols and amphiphilic saponins, with the 70% ethanol extract showing the richest phytochemical profile and strongest α‐amylase inhibition. Its solvent‐dependent bioactive composition suggests potential application in managing postprandial hyperglycemia by modulating dietary starch ...
Keisham Subharani Devi   +3 more
wiley   +1 more source

Potassium phthalimide promoted green multicomponent tandem synthesis of 2-amino-4H-chromenes and 6-amino-4H-pyran-3-carboxylates

open access: yesJournal of Saudi Chemical Society, 2014
A one-pot efficient, green, practical, and environmentally friendly multicomponent synthesis of 5-oxo-4-aryl-5,6,7,8-tetrahydro-4H-chromenes, ethyl-6-amino-4-aryl-5-cyano-2-methyl-4H-pyran-3-carboxylates as well as 2-amino-4-aryl-7-hydroxy-4H-chromene-3 ...
Hamzeh Kiyani, Fatemeh Ghorbani
doaj   +1 more source

Multi component one pot synthesis and characterization of derivatives of 2-amino-7,7- dimethyl-5-oxo-4-phenyl-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile and study of anti-microbial activity

open access: yesBulletin of the Chemical Society of Ethiopia, 2018
An efficient and convenient procedure has been described for one-pot multi-component synthesis of tetrahydrobenzo[b]pyrans known as 2-amino-7,7-dimethyl-5-oxo-4-phenyl-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile which can be obtained from the reaction ...
N. K. Rao   +4 more
doaj   +1 more source

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