Role of acidity in acid-clay catalysts for the phosgene-free synthesis of methylene diphenyl dicarbamate (MDC). [PDF]
Chen P, Qian J, Chen Q, Dai X, He M.
europepmc +1 more source
Click-to-Release Reactions for Tertiary Amines and Pyridines. [PDF]
Chojnacki K +9 more
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Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu +3 more
wiley +1 more source
Imidazo[1,2‑<i>a</i>]pyridines in Medicinal Chemistry: Recent Advances in Synthesis and Biological Activities. [PDF]
Ferreira LAP +6 more
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Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex
The syntheses and the structures of N‐heterocyclic allenes are reported. Allenes bearing fluorenylidene capping groups show markedly bent C═C═C units, a carbene‐like reactivity, and they can act as potent C‐donor ligands for metal complexes. ABSTRACT Allenes typically display a linear geometry. A notable exception occurs in allenes bearing two electron‐
Bastiaan Kooij +4 more
wiley +1 more source
Discovery of 7-(Pyridin-3-yl)thieno[3,2-<i>b</i>]pyridine-5-carboxamides as Negative Allosteric Modulators of Metabotropic Glutamate Receptor Subtype 5. [PDF]
Henderson SH +21 more
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Die geminale Difunktionalisierung leicht verfügbarer Bausteine ermöglicht einen schnellen Zugang zu molekularer Komplexität. Diese Arbeit stellt eine Strategie vor, um zwei unterschiedliche funktionelle Gruppen an einem Carbonylkohlenstoff zu installieren, indem dieser in eine Donor–Donor‐Diazo‐Verbindung überführt wird. Die Methode ist sowohl im Batch‐
Vincent George +13 more
wiley +1 more source
Crystal structure and Hirshfeld surface analysis of ethyl 2-amino-4-(4-chloro-phen-yl)-5,6,7,8,9,10-hexa-hydro-cyclo-octa-[<i>b</i>]pyridine-3-carboxyl-ate. [PDF]
Pazhamalai S +4 more
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