Results 181 to 190 of about 344,103 (291)

Steric Hindrance and Secondary Interactions Govern Reconfiguration Between Two Complex CuI Coordination Cages

open access: yesAngewandte Chemie, EarlyView.
Fine‐tuning steric and C─H···π contacts directs assembly of two CuI cages. An identical naphthylene‐based subcomponent forms a [CuI12L6]12+ pseudo‐hexagonal prism stabilized by 29–32 C─H···π contacts and 12 arene stacking pairs with 6‐methyl‐2‐formylpyridine, whereas the 3‐methyl analog imparts steric clashes, yielding a [CuI8L4]8+ open prism ...
Houyang Xu   +3 more
wiley   +2 more sources

Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation

open access: yesAngewandte Chemie, EarlyView.
A new type of Michael addition based on azide‐to‐diazo conversion is disclosed. This unusual transformation proceeds via 1,4‐addition accompanied by N─N bond cleavage of phosphazide intermediates under practical conditions. The high versatility of the resulting Michael adducts enables the synthesis of a wide variety of organonitrogen compounds ...
Tomoki Mano   +3 more
wiley   +2 more sources

Pyridin [PDF]

open access: yes, 2019
openaire   +1 more source

Hydrogen Isotope Exchange in Pyridine Catalyzed by an Iron(II) Imido Complex: Counterion‐Directed Regioselectivity

open access: yesAngewandte Chemie, EarlyView.
Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng   +6 more
wiley   +2 more sources

Design, synthesis, and biological evaluation of pyridylamide-type neonicotinoid derivatives based on flupyrimin scaffold. [PDF]

open access: yesBMC Chem
Fang Q   +9 more
europepmc   +1 more source

Pyridine [PDF]

open access: yesChemical & Engineering News Archive, 1975
openaire   +1 more source

Solvent Effects on the Photophysical Properties of Unexplored Imidazo[1,2‑<i>a</i>]pyridine Derivatives. [PDF]

open access: yesACS Omega
Justino Garcia Praciano VH   +4 more
europepmc   +1 more source

1-Alkoxyamino-4-dimethylaminopyridinium derivatives as new representatives of O–N–N⁺ geminal systems and their structure [PDF]

open access: yes, 2012
Gerasimenko, M. V.   +7 more
core  

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