Heterogeneous photocatalytic C4 remote fluorosulfonamidation of pyridines. [PDF]
Xiang P +7 more
europepmc +1 more source
We report a pair of interconvertible palladium(II) cages assembled from an asymmetric ligand, whose switching is triggered by specific counter‐anions, tetrafluoroborate (BF4−) and bis(trifluoromethanesulfonyl)imide (NTf2−). Their complementary guest preferences enable orthogonal, multi‐cycle catch‐and‐release, exemplified by the selective purification ...
Zhe Li +2 more
wiley +2 more sources
Integrative analyses of the transcriptome and metabolome of Huzhang (Pinellia pedatisecta Schott) uncover the molecular genetic basis of its medicinal properties. [PDF]
Pan C, Chen J, Qian Z.
europepmc +1 more source
Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth +2 more
wiley +2 more sources
Atomic-Level Insights into Thermal Carbonization of Ethynyl-Containing Boron Compounds. [PDF]
Ohkura K +5 more
europepmc +1 more source
Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways
A regiodivergent strategy converts a single N‐aminoquinolinium precursor into either C3‐ or C4‐aminated quinolines. Nucleophile‐induced dearomatization diverges into light‐driven N‐centered radical capture (C3) or base‐promoted SNAr (C4), enabling rapid assembly of aminoquinoline libraries and late‐stage diversification.
Ye‐Eun Kim +3 more
wiley +2 more sources
Coordination versatility and enhanced bioactivity of Co<sup>2+</sup>, Cu<sup>2+</sup> and Cd<sup>2+</sup> complexes derived from pyridyl Schiff base: structural, electronic and electrochemical insights. [PDF]
Elshewemy AK +6 more
europepmc +1 more source
Depolymerization and Reuse of Polycarbonates: Emerging Classes, Mechanisms and Challenges
This review collects the latest developments in the area of chemical and catalytic polycarbonate recycling strategies and includes the controlled degradation of similar types of macromolecules. Apart from the main strategies for deconstruction, the key mechanistic features of these depolymerization processes are also discussed together with the ...
Davide Rigo +4 more
wiley +2 more sources
Encapsulated Non-Exchangeable Na<sup>+</sup> Ions Determining the Upper Limit of Al Inclusion in FAU-A Multiscale Simulation. [PDF]
Dong Q +8 more
europepmc +1 more source

