Results 191 to 200 of about 205,200 (319)

Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side‐Chain Structures

open access: yesAngewandte Chemie, EarlyView.
We developed a novel domino polymerization to synthesize reductively degradable poly(disulfide)s with tunable side chains. A novel monomer bearing thiolactone and pyridyl disulfide groups reacts with various amines, enabling continuous ring‐opening and disulfide exchange.
Yukiya Kitayama   +2 more
wiley   +2 more sources

Heterogeneous photocatalytic C4 remote fluorosulfonamidation of pyridines. [PDF]

open access: yesChem Sci
Xiang P   +7 more
europepmc   +1 more source

Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross‐Coupling

open access: yesAngewandte Chemie, EarlyView.
Hard‐to‐access (hetero)aryl sulfonium salts are prepared using stable methoxysulfonium salts in combination with the magnesiation of (hetero)aryl bromides. The approach allows access to aryl sulfonium salts bearing electron‐deficient (hetero)aryl rings, or electron‐rich aryl motifs in which the sulfonium motif resides at an alternative position on the ...
Rachel E. Brown   +4 more
wiley   +2 more sources

Pyridine

open access: yesJournal of Synthetic Organic Chemistry, Japan, 1982
Meera Asthana, L.M. Mukherjee
openaire   +3 more sources

Anion‐Controlled Structural Interconversion of Palladium Cages Enables Separations by Selective Guest Capture and Release

open access: yesAngewandte Chemie, EarlyView.
We report a pair of interconvertible palladium(II) cages assembled from an asymmetric ligand, whose switching is triggered by specific counter‐anions, tetrafluoroborate (BF4−) and bis(trifluoromethanesulfonyl)imide (NTf2−). Their complementary guest preferences enable orthogonal, multi‐cycle catch‐and‐release, exemplified by the selective purification ...
Zhe Li   +2 more
wiley   +2 more sources

Heterobenzyl Chlorides as Linchpins for C-H Arylation via Sequential C-H Chlorination/Cross-Electrophile Coupling. [PDF]

open access: yesACS Catal
Floreancig JT   +6 more
europepmc   +1 more source

Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling

open access: yesAngewandte Chemie, EarlyView.
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth   +2 more
wiley   +2 more sources

Synthesis and <i>meta</i>-Amination of Pyridines via Multicomponent Cascade Reaction. [PDF]

open access: yesOrg Lett
Francisco TN   +7 more
europepmc   +1 more source

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