We developed a novel domino polymerization to synthesize reductively degradable poly(disulfide)s with tunable side chains. A novel monomer bearing thiolactone and pyridyl disulfide groups reacts with various amines, enabling continuous ring‐opening and disulfide exchange.
Yukiya Kitayama +2 more
wiley +2 more sources
Heterogeneous photocatalytic C4 remote fluorosulfonamidation of pyridines. [PDF]
Xiang P +7 more
europepmc +1 more source
Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross‐Coupling
Hard‐to‐access (hetero)aryl sulfonium salts are prepared using stable methoxysulfonium salts in combination with the magnesiation of (hetero)aryl bromides. The approach allows access to aryl sulfonium salts bearing electron‐deficient (hetero)aryl rings, or electron‐rich aryl motifs in which the sulfonium motif resides at an alternative position on the ...
Rachel E. Brown +4 more
wiley +2 more sources
Meera Asthana, L.M. Mukherjee
openaire +3 more sources
Nanomagnetic 4-amino-3-hydroxynaphthalene-1-sulfonic as an efficient heterogeneous catalyst for multicomponent synthesis of 2-amino-3-cyano-4,6-diarylpyridines under green conditions. [PDF]
Alnuwaiser MA +5 more
europepmc +1 more source
We report a pair of interconvertible palladium(II) cages assembled from an asymmetric ligand, whose switching is triggered by specific counter‐anions, tetrafluoroborate (BF4−) and bis(trifluoromethanesulfonyl)imide (NTf2−). Their complementary guest preferences enable orthogonal, multi‐cycle catch‐and‐release, exemplified by the selective purification ...
Zhe Li +2 more
wiley +2 more sources
Heterobenzyl Chlorides as Linchpins for C-H Arylation via Sequential C-H Chlorination/Cross-Electrophile Coupling. [PDF]
Floreancig JT +6 more
europepmc +1 more source
Progress towards metal-free radical alkylations of quinones under mild conditions [PDF]
Baxter, Ryan D, Galloway, Jordan D
core +1 more source
Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth +2 more
wiley +2 more sources
Synthesis and <i>meta</i>-Amination of Pyridines via Multicomponent Cascade Reaction. [PDF]
Francisco TN +7 more
europepmc +1 more source

