Racemisation of Amino Acids: From Synthetic Challenge to Biological Significance
Racemisation, once considered an undesirable synthetic side reaction, also occurs naturally in amino acids and influences biological processes. Evidence links stereochemical conversion to ageing, protein turnover, and cellular development. This review examines mechanisms, control strategies in synthesis, applications and implications in physiology ...
Othman Al Musaimi
wiley +1 more source
A Nonenzymatic Analogue of the Biosynthesis of Pyridoxal Vitamers. [PDF]
Nogal N, Basar AB, Minic Z, Moran J.
europepmc +1 more source
Immune-metabolic crosstalk in rheumatoid arthritis: mediation effects of plasma metabolites on inflammatory cytokines. [PDF]
Liang Y +5 more
europepmc +1 more source
Exploring Diverse Glycone Preferences of Aspergillus rutinosidases
Rutinosidases from Aspergillus niger (AnRut) and A. oryzae (AoRut) catalyze hydrolysis and transglycosylation with non‐natural glycosides as donors, enabling glycosylation of alcoholic and phenolic acceptors. AnRut exhibits broad glycone promiscuity, while AoRut has a narrower substrate scope.
Jitka Brouzdová +9 more
wiley +1 more source
The first report of primary hypotonia with abnormal electromyogram and CBS mutation in a Chinese child. [PDF]
Zhang Z, Xu S, Wu T, Xu W, Wu B, Yang C.
europepmc +1 more source
Uptake of Pyridoxal and Pyridoxal Phosphate by Ehrlich Ascites Tumor Cells
Pal, P, Christensen, H N
openaire +2 more sources
Electrolyte Design Strategies for Static Shuttle‐Free and Long‐Life Aqueous Zinc‐Iodine Batteries
This review systematically summarizes recent advances in electrolyte design for static aqueous Zn‐I2 batteries, highlighting solvation regulation and interfacial engineering strategies to control reaction kinetics, suppress iodine shuttling, enhance energy density, and stabilize multi‐electron iodine redox chemistry for durable, high‐performance energy
Qianqin Zhou +3 more
wiley +1 more source
Amphiphilic Macromolecular Dendritic Antioxidants with Surfaces Coated in Hybrid Phenolic Units That Provide Anti-Inflammatory Properties. [PDF]
Agbemade B +6 more
europepmc +1 more source
We demonstrate that Cars2, a cysteine catabolic enzyme in mouse iBAT, is critical for cold tolerance and brown adipocyte differentiation. Through its CPERS activity, Cars2 produces CysSSH/H2S to induce EBF2 persulfidation, promoting its interaction with PPARγ and BRG1 to enhance thermogenic gene expression.
Xin Peng +8 more
wiley +1 more source

