Results 71 to 80 of about 17,027 (206)

Nickel ferrite nanoparticles doped on hollow carbon microspheres as a novel reusable catalyst for synthesis of N-substituted pyrrole derivatives

open access: yesScientific Reports, 2023
Pyrroles are widely spread worldwide because of their critical applications, especially pharmacology. An expedition method for one-pot synthesis of N-substituted pyrrole derivatives has been presented by a reaction between 2,5-dimethoxytetrahydrofuran ...
Setareh Mousavi   +3 more
doaj   +1 more source

Development of Novel Pyrrole Derivatives and Their Cinnamic Hybrids as Dual COX-2/LOX Inhibitors

open access: yesMolecules, 2023
Molecular hybridization has emerged as a promising approach in the treatment of diseases exhibiting multifactorial etiology. With regard to this, dual cyclooxygenase-2/lipoxygenase (COX-2/LOX) inhibitors could be considered a safe alternative to ...
Viola Noti   +2 more
doaj   +1 more source

Selective synthesis of functionalized pyrroles from 3-aza-1,5-enynes [PDF]

open access: yes, 2016
2-Trifluoromethyl-5-(arylsulfonyl)methyl pyrroles and 2-trifluoromethyl-4-(arylsulfonyl) methyl pyrroles were selectively synthesized from trifluoromethyl-substituted 3-aza-1,5-enynes via a cyclization/sulfonyl group migration cascade catalyzed by ...
Wan, Boshun   +5 more
core   +1 more source

Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles [PDF]

open access: yes, 2016
The synthesis of highly functionalized pyrroles has been achieved by reaction of rhodium-stabilized imino-carbenes with furans. The reaction features an initial [3+2] annulation to form bicyclic hemiaminals, followed by ring opening to generate ...
Samantha A. Green (1977208)   +2 more
core   +1 more source

Deproto-metallation of N-arylated pyrroles and indoles using a mixed lithium–zinc base and regioselectivity-computed CH acidity relationship

open access: yesBeilstein Journal of Organic Chemistry, 2015
The synthesis of N-arylated pyrroles and indoles is documented, as well as their functionalization by deprotonative metallation using the base in situ prepared from LiTMP and ZnCl2·TMEDA (1/3 equiv).
Mohamed Yacine Ameur Messaoud   +12 more
doaj   +1 more source

Carbohydrate-auxiliary assisted preparation of enantiopure 1,2-oxazine derivatives and aminopolyols

open access: yesBeilstein Journal of Organic Chemistry, 2012
An approach to enantiopure hydroxylated 2H-1,2-oxazine derivatives is presented utilizing the [3 + 3] cyclisation of lithiated alkoxyallenes and an L-erythrose-derived N-glycosyl nitrone as precursors.
Marcin Jasiński   +2 more
doaj   +1 more source

Photofragment slice imaging studies of pyrrole and the Xe⋯pyrrole cluster [PDF]

open access: yesThe Journal of Chemical Physics, 2007
The photolysis of pyrrole has been studied in a molecular beam at wavelengths of 250, 240, and 193.3nm, using two different carrier gases, He and Xe. A broad bimodal distribution of H-atom fragment velocities has been observed at all wavelengths. Near threshold at both 240 and 250nm, sharp features have been observed in the fast part of the H-atom ...
Rubio-Lago, L   +12 more
openaire   +3 more sources

An efficient and facile access to highly functionalized pyrrole derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2018
A straightforward and one-pot synthesis of pyrrolo[3,4-c]pyrrole-1,3-diones via Ag(I)-catalyzed 1,3-dipolar cycloaddition of azomethine ylides with N-alkyl maleimide, followed by readily complete oxidation with DDQ, has been successfully developed ...
Meng Gao   +5 more
doaj   +1 more source

Gold(I)-Catalyzed Intra- and Intermolecular Alkenylations of beta-Yne-pyrroles: Facile Formation of Fused Cycloheptapyrroles and Functionalized Pyrroles [PDF]

open access: yes, 2014
An efficient gold(I)-catalyzed alkenylation of beta-alkyne-substituted pyrroles is reported. The intramolecular reaction gives straightforward access to different types of seven-membered-ring-fused pyrroles with endo-selectivity, and the intermolecular ...
Wu, Fan   +5 more
core   +1 more source

Three-component reactions of aromatic amines, 1,3-dicarbonyl compounds, and α-bromoacetaldehyde acetal to access N-(hetero)aryl-4,5-unsubstituted pyrroles

open access: yesBeilstein Journal of Organic Chemistry, 2020
N-(Hetero)aryl-4,5-unsubstituted pyrroles were synthesized from (hetero)arylamines, 1,3-dicarbonyl compounds, and α-bromoacetaldehyde acetal by using aluminum(III) chloride as a Lewis acid catalyst through [1 + 2 + 2] annulation.
Wenbo Huang   +5 more
doaj   +1 more source

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