Results 71 to 80 of about 4,019 (234)
An efficient artificial copper‐dependent Michaelase featuring a metal‐binding unnatural amino acid, e. g. bipyridyl alanine (BpyA), was optimized through directed evolution and applied in catalytic asymmetric additions of 2‐acetyl azaarenes to nitroalkenes.
Ru Jiang+3 more
wiley +2 more sources
Total Synthesis of Rhazinilam through Gold-Catalyzed Cycloisomerization–Sulfonyl Migration and Palladium-Catalyzed Suzuki–Miyaura Coupling of Pyrrolyl Sulfonates [PDF]
International audienceWe report the first general conditions for the challenging Suzuki-Miyaura reaction with pyrrole-related sulfonate coupling partners (24 examples, 60-97%).
Blanc, Aurelien+3 more
core +2 more sources
A comparative analysis of cis‐ and trans‐configured hydroxyl‐functionalized cyclohexylammonium chloride (ACHACl) ligands reveals distinct adsorption behaviors on [PbI6]4− octahedra during 2D/3D perovskite heterojunction formation. The cis isomer exhibits stronger surface interaction, leading to more effective defect passivation, including Pb0 ...
Yonghoon Jung+5 more
wiley +1 more source
Synthesis of Functionalized Pyrrolidinone Scaffolds via Smiles-Truce Cascade. [PDF]
Sephton T+3 more
europepmc +1 more source
Stereoselective synthesis of pyrrolidinones via nitro-Mannich reaction: towards the synthesis of popolohuanone E [PDF]
Part 1: The first section of this thesis details the stereoselective synthesis of pyrrolidinones via the nitro-Mannich reaction. Expanding on previous work within the Anderson group, conjugate addition of a diorganozinc species to nitroacrylate 141 ...
Horsfall, L.R.
core
Composition‐tuned (ReMoV)X2 (X = S, Se) ternary alloy nanosheets are synthesized using solution reactions. A homogeneous atomic mixing occurred in the metallic 1T phase. The electrocatalytic activity toward the acidic hydrogen evolution reaction is enhanced for the sulfide nanosheets.
Junaid Ihsan+10 more
wiley +1 more source
Palladium(II)-Catalyzed C(sp3)–H Activation of N,O-Ketals towards a Method for the β-Functionalization of Ketones [PDF]
A method for the formal β-functionalization of aliphatic ketones via a palladium-catalyzed sp3 C–H activation pathway is reported. An N,O-ketal directs an aliphatic C–H carbonylation to form γ-lactams which upon hydrolysis generate γ-keto carboxylic ...
Calleja, Jonas+2 more
core +1 more source
Autonomous Artificial Molecular Motors and Pumps
Autonomous energy consumption is the only way to introduce molecular motors into more sophisticated, larger systems, capable of life‐like behavior. We reviewed a selection of the most recent advances in the field molecular motors focusing on those capable of performing continuous and autonomous motion under constant experimental conditions, that is ...
Chiara Taticchi+2 more
wiley +1 more source
Postirradiation polymerization of acrylic acid and vinyl pyrrolidinone on polypropylene [PDF]
You‐Lo Hsieh, M. Shinawatra
openalex +1 more source
While SGLT2 accounts for >90% of kidney glucose reabsorption, its pharmacological inhibition or genetic knockdown reduces glucose reabsorption by only 50%. We found that the SGLT2 inhibitor, dapagliflozin, induced an early, transient hyperplastic response in the SGLT1‐expressing S3 segment of the proximal tubule followed by an increase in its length ...
Ellen Wu+14 more
wiley +1 more source