Results 111 to 120 of about 19,883 (275)

Selective Formation of a 1,2‐Diborane(4) and Alcohol‐Driven B─B Bond Cleavage to Generate H2

open access: yesChemistry – A European Journal, EarlyView.
Diborane(4) chemistry reveals unusual reactivity of electron‐deficient p‐block compounds. Reaction of B2Cat2 (Cat = benzene‐1,2‐diolate) with mesityllithium (MesLi; Mes = 2,4,6‐trimethylphenyl) gives a rare 1,2‐diborane(4) featuring a catecholate ligand. Alcoholysis cleaves the B─B bond and ultimately generates H2.
Rayni P. Noriega   +2 more
wiley   +1 more source

Synthesis of a Novel Series of Pyrimido- and Triazino[4,5-b] Quinolines

open access: yes, 2010
New tetrahydropyrimido[4,5- b]quinolines, hexahydropyrimido[4,5- b]quinolines, a thioxohexahydropyrimido[4,5- b] quinoline, an octahydropyrimido[4,5- b]quinoline and a tetrahydro[1,2,3]triazino[4,5- b]quinoline have been synthesised.
Ahmed H. Moustafa, Said A. Said
core   +1 more source

1,7-Hydride transfer-involved dearomatization of quinolines to access C3-spiro hydroquinolines

open access: yesGreen Synthesis and Catalysis
1,7-Hydride transfer-involved dearomatization of quinolines toward C3-spiro hydroquinoline derivatives has been developed. This method offers a protocol to achieve the dearomatization of electron-deficient arenes via the redox-neutral hydride transfer ...
Da-Ying Shao   +5 more
doaj   +1 more source

Enhancement of the Plant‐Accessible Phosphate Fraction in Sewage Sludge Ashes by Na+ or K+ Addition Prior to Combustion

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The addition of Na2CO3 or K2CO3 to sewage sludge prior to combustion leads to the production of ashes containing phosphate in the form of buchwaldite‐like phases (Ca(Na/K)PO4). Compared to conventional sewage sludge mono‐ashes, such Na‐ or K‐ashes show greatly increased P‐solubilities and proved to be potent P‐fertiliser materials in greenhouse ...
Lorenz Bier‐Schorr   +4 more
wiley   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Divergent Synthesis of Quinolines: Exploiting the Duality of Free Radicals

open access: yes
Herein, we present a green scheme for the divergent synthesis of two polysubstituted quinolines from a singular substrate via exploiting free-radical duality.
Runwei Jiao (8593647)   +8 more
core   +1 more source

Dearomative dimerization of quinolines and their skeletal rearrangement to indoles triggered by single-electron transfer [PDF]

open access: yes
Dearomatization of two-dimensional (2D) planar aromatic feedstocks enables the introduction of three-dimensional (3D) vectors to new molecular scaffolds, vastly expanding the chemical space for drug discovery.
Shunsuke, Chiba   +4 more
core   +2 more sources

Photocatalyst‐Free Trifluoromethylation of Indolizines Through an Electron Donor–Acceptor Complex

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new photocatalyst‐free pathway for the direct C‐3‐trifluoromethylation of indolizines and imidazo[1,2‐a]pyridines through an electron donor–acceptor (EDA) complex is studied. This regioselective reaction supports a wide range of functional groups, indicating good versatility and robustness.
Corinne Coutant   +7 more
wiley   +1 more source

Reductive Cyclization of o-Nitrophenyl Propargyl Alcohols:  Facile Synthesis of Substituted Quinolines†

open access: yes, 2016
Reduction of secondary and tertiary o-nitrophenyl propargyl alcohols followed by acid-catalyzed Meyer−Schuster rearrangement gave 2-substituted and 2,4-disubstituted quinolines, respectively.
Matthew J. Sandelier (2480197)   +1 more
core   +1 more source

Photocatalysis‐Triggered Click Reactions and Applications

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Photoclick chemistry offers broad applications ranging from materials science to bioconjugation, with precise spatiotemporal control over click reactions. Initially limited to UV activation, recent advances have extended photoclick processes to the visible and NIR regions thanks to the photocatalysis.
Margaux Walter   +2 more
wiley   +1 more source

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