Modular and diverse synthesis of oxaheterocycles <i>via</i> Pd-catalyzed migratory 1,<i>n</i>-cycloannulation of alkenes. [PDF]
Wang JP, Wu Y, Wang P.
europepmc +1 more source
Regioselective Sesquiterpene Hydroxylation Directed by Tunnel Remodeling in Rieske Oxygenases. [PDF]
Berger JB +6 more
europepmc +1 more source
Copper-Mediated Late-Stage Radical Trifluoromethylation of Pyrazole-Type Scaffolds. [PDF]
Eisen LS +4 more
europepmc +1 more source
Rhodium-Catalyzed Reductive Carbonylative Cyclization of Aryl Alkynes with Hydrosilanes via C-H Activation to Access Silyl-Substituted Indanones. [PDF]
Zhu F, Zhou M, Wu XF.
europepmc +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source
A General Group Testing Strategy for Discovering Chemical Cooperativity
A combinatorial design theory‐based group testing strategy coupled with luminescence screening to uncover cooperative interactions in a large combinatorial space. Iterative deconvolution identifies reactive molecular pairs and enables the discovery of trifluoromethylthiolation (SCF3) reagents.
Philipp M. Pflüger +9 more
wiley +2 more sources
Pd-catalyzed regiodivergent arylation of cyclic allylboronates. [PDF]
Zhang C +3 more
europepmc +1 more source
The synthesis of aromatic amino alcohols via a combination of an unspecific peroxygenase‐catalysed reaction, oxyfunctionalization, and addition of selected nucleophiles and electrophiles in a highly atom‐efficient manner was investigated. This study presents the design to aim for an atom‐efficient chemo‐enzymatic synthesis route towards aromatic amino ...
Simon Last +3 more
wiley +1 more source
Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle
This work demonstrates the nontrivial reactivity of pyridine incorporated into a porphyrin framework. The most significant achievement is the contraction of the six‐membered ring to a pyrrole ring, which is a phenomenon of great interest to researchers in this field.
Paulina Krzyszowska +5 more
wiley +2 more sources
Sulfonyl-Directed Photoinduced Dehydro-Diels-Alder Reaction of Aryl Maleimides: Enabling Regioselective Naphthalene Synthesis. [PDF]
Song XH +5 more
europepmc +1 more source

