Results 21 to 30 of about 9,389 (255)

Hoveyda–Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable, industrially scalable, highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors

open access: yesBeilstein Journal of Organic Chemistry, 2019
A novel and efficient approach to the synthesis of 2-vinylbenzylamines is reported. This involves obtaining 2-vinylbenzylamine ligands from tetrahydroisoquinoline by alkylation and reduction followed by the Hofmann cleavage.
Kirill B. Polyanskii   +6 more
doaj   +1 more source

First Total Synthesis of Cryptopyranmoscatone A3 and Crypto­pyranmoscatone B4

open access: yesSynOpen, 2018
The first total synthesis of cryptopyranmoscatones A3 and B4 has been accomplished from d-ribose or but-3-ynol. The key steps involved in the synthesis are oxa-Michael addition, highly diastereo­selective Brown allylation, and ring closing metathesis ...
A. Maheswara Reddy, Gowravaram Sabitha
doaj   +1 more source

Tandem Cyclopropanation/Ring-Closing Metathesis of Dienynes [PDF]

open access: yesJournal of the American Chemical Society, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Brian P, Peppers, Steven T, Diver
openaire   +2 more sources

A New Variant of Fused Cyclic Ether Synthesis Based on Ireland-Claisen Rearrangement and RCM

open access: yesNatural Product Communications, 2013
A new variant of fused cyclic ether synthesis based on Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed. The Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed.
Daisuke Domon   +5 more
doaj   +1 more source

Ring closing metathesis reactions of α-methylene-β-lactams : application to the synthesis of a simplified phyllostictine analogue with herbicidal activity [PDF]

open access: yes, 2015
Ring closing metathesis (RCM) reactions of α-methylene-β-lactams are used to construct strained 11- and 12-membered macrocycles that mimic key structural elements of phyllostictine A.
Napier, R. (Richard)   +15 more
core   +1 more source

Light-induced olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2010
Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful.
Yuval Vidavsky, N. Gabriel Lemcoff
doaj   +1 more source

Stereoselectivity of Macrocyclic Ring-Closing Olefin Metathesis [PDF]

open access: yesOrganic Letters, 2000
[reaction: see text] Macrocyclic ring-closing olefin metathesis using ruthenium catalyst 3 was performed to produce a 14-membered lactone. The E/Z ratio of lactone was high regardless of the R group (auxiliary) or the initial alkene stereochemistry.
Lee, Choon Woo, Grubbs, Robert H.
openaire   +4 more sources

Ring Rearrangement Metathesis in 7-Oxabicyclo[2.2.1]heptene (7-Oxanorbornene) Derivatives. Some Applications in Natural Product Chemistry

open access: yesNatural Product Communications, 2017
Metathesis reactions is firmly established as a valuable synthetic tool in organic chemistry, clearly comparable with the venerable Diels-Alder and Wittig reactions and, more recently, with the metal-catalyzed cross-coupling reactions.
Silvia Roscales, Joaquín Plumet
doaj   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

Polycyclic Aromatic Hydrocarbons by Ring‐Closing Metathesis. [PDF]

open access: yesChemInform, 2005
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
Margel C, Bonifacio   +3 more
openaire   +2 more sources

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