Results 31 to 40 of about 9,389 (255)

Valency‐Controlled Multiphotochromism: Gated Switching and Photoswitchable Lewis Superacidity at Silicon

open access: yesAngewandte Chemie, EarlyView.
Multiphotochromic switching is controlled by silicon valency in a diarylethene‐based molecular architecture. Lewis base coordination gates electronic communication between the photochromic units, thereby enabling selective access to distinct switching states.
Lennart Stoess   +2 more
wiley   +2 more sources

Olefin metathesis in nano-sized systems

open access: yesBeilstein Journal of Organic Chemistry, 2011
The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade.
Didier Astruc   +7 more
doaj   +1 more source

Multiple Olefin Metathesis Polymerization That Combines All Three Olefin Metathesis Transformations: Ring-Opening, Ring-Closing, and Cross Metathesis [PDF]

open access: yes, 2015
We demonstrated tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization of monomers containing two cyclopentene moieties and postmodification via insertion polymerization.
Tae-Lim Choi (1500892)   +9 more
core   +1 more source

Enzymatic Encoding of Topology in an Intrinsically Disordered Single‐Chain Protein

open access: yesAngewandte Chemie, EarlyView.
Enzymatic intramolecular cross‐linking enables topology control in intrinsically disordered proteins, yielding SCNPs with reproducible cavity architectures. Using β‐casein and microbial transglutaminase, sparse, sequence‐resolved constraints drive compact collapse without inducing secondary structure.
Joshua Johani   +9 more
wiley   +2 more sources

Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers

open access: yes, 2018
We report the preparation of cyclic ferrocenyl olefins with various substituents and different ring sizes by ring-closing metathesis (RCM). These ferrocene-containing monomers were subject to ring-opening metathesis polymerization (ROMP), leading to main-
Yudi Zhang (5747321)   +13 more
core   +1 more source

Anionic T‐Shaped Platinum(0) Pincer Complexes and Platinum(I) Intermediates in Radical Reactions With Alkyl Halides

open access: yesAngewandte Chemie, EarlyView.
Two anionic, T‐shaped, d10 platinum(0) complexes containing a PNP pincer ligand have been isolated and characterized. These complexes react with aliphatic C‐Br bonds under formation of a platinum(II) bromide and an alkyl complex, as well as the homocoupled hydrocarbons.
Vincenz J. Kohler   +6 more
wiley   +2 more sources

Domino ring-opening–ring-closing enyne metathesis vs enyne metathesis of norbornene derivatives with alkynyl side chains. Construction of condensed polycarbocycles

open access: yesBeilstein Journal of Organic Chemistry, 2018
The metathesis of norbornene derivatives with alkynyl side-chain with Grubbs’ ruthenium alkylidine as catalyst has been investigated with the objective of constructing condensed polycyclic structures.
Ritabrata Datta, Subrata Ghosh
doaj   +1 more source

Catalyst Hide‐and‐Seek Beneath Porous Support Surfaces: Pinpointing Active Site Distribution Through Resonance Energy Transfer

open access: yesAngewandte Chemie, EarlyView.
Like a shark playing hide‐and‐seek in a coral reef, energy transfer (ET) finds hidden “fish” catalysts in the porous support “reef.” ET allows catalytic species to be precisely mapped, revealing whether they reside near the surface, deep in the pores, or are uniformly distributed. This approach ensures controlled catalyst distribution, highlighting how
Buddhima K. P. Maldeni Kankanamalage   +8 more
wiley   +2 more sources

Design and synthesis of hybrid cyclophanes containing thiophene and indole units via Grignard reaction, Fischer indolization and ring-closing metathesis as key steps

open access: yesBeilstein Journal of Organic Chemistry, 2015
We demonstrate a new synthetic strategy to cyclophanes containing thiophene and indole moieties via Grignard addition, Fischer indolization and ring-closing metathesis as key steps.
Sambasivarao Kotha   +2 more
doaj   +1 more source

Design of Heterogeneous Hoveyda–Grubbs Second-Generation Catalyst–Lipase Conjugates

open access: yesMolecules, 2016
Heterogeneous catalysts have been synthesized by the conjugation of Hoveyda–Grubbs second-generation catalyst with a lipase. The catalytic properties of the organometallic compound in solution were firstly optimized, evaluating the activity of Ru in the ...
Anthony Neville   +2 more
doaj   +1 more source

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