Results 41 to 50 of about 9,389 (255)

Synthesis of Pentacycloundecane (PCUD) Based Spiro-Pyrano-Cage Framework via Ring-Closing Metathesis

open access: yesMolbank, 2023
Here, we demonstrate a short synthetic route to pyrano cage systems containing pentacycloundecane units by employing ring-closing metathesis (RCM) as a key step.
Sambasivarao Kotha   +2 more
doaj   +1 more source

Tandem Cyclopropanation/Ring-Closing Metathesis of Dienynes

open access: yes, 2016
Certain dienynes give cyclorearrangement by tandem cyclopropanation/ring-closing alkene metathesis, triggered by either a ruthenium carbene or noncarbene ruthenium(II) precatalyst.
Steven T. Diver (1667287)   +1 more
core   +1 more source

Phase‐Pure and Size‐Tunable Tin Halide Perovskite Quantum Dots

open access: yesAdvanced Materials, EarlyView.
A trioctylphosphine oxide modulated protocol allows for the synthesis and study of the optical properties of a broad library of tin halide perovskite quantum dots across multiple A‐ and X‐site compositions with precise size tuning while eliminating unwanted 2D phases.
Ole F. Dressler   +7 more
wiley   +1 more source

Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries

open access: yesAngewandte Chemie, EarlyView.
This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho   +4 more
wiley   +2 more sources

New library of aminosulfonyl-tagged Hoveyda–Grubbs type complexes: Synthesis, kinetic studies and activity in olefin metathesis transformations

open access: yesBeilstein Journal of Organic Chemistry, 2010
Seven novel Hoveyda–Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda’s precatalyst.
Etienne Borré   +3 more
doaj   +1 more source

Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis

open access: yes, 2016
Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing ...
Richard R. Schrock (1295601)   +4 more
core   +1 more source

A Super‐Adhesive Air Filter With Capillarity‐Mediated Spontaneous Particle Absorption via Dynamic Bond Exchange

open access: yesAdvanced Materials, EarlyView.
We address the inherently weak particle adhesion of conventional air filters by coating a dynamically crosslinked adhesive layer that delivers capillarity‐driven strong adhesion and particle absorption mediated by dynamic bond exchange. The resulting enhancement in particle adhesion enables efficient ultrafast (up to 20 m s−1) and omnidirectional ...
Junyong Park   +11 more
wiley   +1 more source

Mechanistic Insight Into the Polymorph‐Dependent Photosalient Effect of a White Light or Two‐Photon Activated Photoreactive Molecular Salt

open access: yesAngewandte Chemie, EarlyView.
Photocycloaddition in stilbene‐type salt polymorphs exhibit distinct light‐driven responses: OHT‐TI shows a violent photosalient effect under visible and NIR (two‐photon) irradiation, whereas OHT‐TII reacts statically. Packing and computational analysis reveals that shell‐like structures in OHT‐TI frustrate structural relaxation, accumulating explosive
Emanuela Santagata   +10 more
wiley   +2 more sources

Metátese de olefinas aplicada ao fechamento de anéis: uma ferramenta poderosa para a síntese de macrociclos naturais Ring-closing olefin metathesis: a powerful tool for the synthesis of natural macrocycles

open access: yesQuímica Nova, 2008
For a quarter of a century, metathesis has become indispensable for the synthesis of natural and non-natural products, particularly of biologically active compounds.
Anderson Rouge dos Santos   +2 more
doaj   +1 more source

Fast Initiating Furan-Containing Hoveyda-Type Complexes: Synthesis and Applications in Metathesis Reactions

open access: yesChemistry, 2022
Two new ruthenium complexes with chelating-ether benzylidene ligands bearing a furan moiety were synthesized and characterized, including X-ray crystallography.
Maryana Nadirova   +3 more
doaj   +1 more source

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