Results 31 to 40 of about 108,684 (302)

A Network for Advancing Dendrochronology, Dendrochemistry and Dendrohydrology in South America

open access: yes, 2020
Tree-ring research (TRR) in South America (SA) continues to make important contributions in multiple sub-disciplines, including dendrochemistry and dendrohydrology.
Aguilera-Betti I.   +3 more
core   +1 more source

Ring-Expansion of Thioacetal Ring via Bicyclosulfonium Ylide. Effect of Protic Nucleophile on Ylide Intermediate

open access: yes, 2016
The reaction of 2-(3-diazo-2-oxopropane-1-yl)-2-methyldithiolane 9a, 2-(4-diazo-3-oxobutane-2-yl)-2-methyldithiolane 9c, and 2-(3-diazo-2-oxopropane-1-yl)-2-methyl-1,3-dithiane 9b with Rh2(OAc)4 gave three-carbon ring-expansion products dithiocan-2-en-1 ...
Takashi Mori (214524)   +2 more
core   +1 more source

Synthesis of macrocyclic and medium-sized ring thiolactones via the ring expansion of lactams [PDF]

open access: yes, 2021
A side chain insertion method for the ring expansion of lactams into macrocyclic thiolactones is reported, that can also be incorporated into Successive Ring Expansion (SuRE) sequences.
Unsworth, William P   +4 more
core   +1 more source

A Tandem Photocycloaddition—Ring Expansion Strategy for the Synthesis of Fused [5.3.0] Triketone

open access: yesMolbank
A tandem synthetic sequence involving photo-induced intramolecular [2+2] cycloaddition followed by acid-promoted ring expansion was developed to access the novel bicyclic triketone framework.
Xin-Yi Hsiao   +2 more
doaj   +1 more source

Oxidative Ring Expansion of Cyclobutanols: Access to Functionalized 1,2-Dioxanes

open access: yes, 2020
Cyclobutanols undergo an oxidative ring expansion into 1,2-dioxanols by using Co(acac)2 and triplet oxygen (3O2) as radical promoters. The formation of an alkoxy radical drives to the regioselective break of the strained ring with stabilization of a new ...
Bruno, Figadère   +4 more
core   +1 more source

[3 + 4] Annulation of Bromoenals and 1,2-Benzenedithiol: Base-Promoted [2 + 4] Reaction and N‑Heterocyclic Carbene-Catalyzed Ring-Expansion

open access: yes, 2018
The [3 + 4] and [2 + 4] annulations of bromoenals and 1,2-benzenedithiol were developed in the presence or absence of N-heterocyclic carbene, respectively.
Xiang-Yu Chen (2226904)   +2 more
core   +2 more sources

Emapalumab for Immune Effector Cell‐Associated Hemophagocytic Lymphohistiocytosis‐Like Syndrome Following CD19‐Directed CAR‐T in Two Patients With B‐ALL: Clinical and Biomarker Correlates

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Immune effector cell‐associated hemophagocytic lymphohistiocytosis‐like syndrome (IEC‐HS) is a life‐threatening hyperinflammatory toxicity distinct from cytokine release syndrome (CRS) and neurotoxicity following chimeric antigen receptor T‐cell (CAR‐T) therapy. In a single‐institution retrospective cohort of pediatric and young adult patients
Thomas J. Galletta   +6 more
wiley   +1 more source

Ring expansion reactions of P=O-containing molecules [PDF]

open access: yes, 2023
A series of ring expansion reactions of P=O-containing molecules have been developed for the synthesis of medium-sized ring cyclic phosphonate esters and phosphonamidates. The reactivity trends initially appear to be counter-intuitive, compared with more
Unsworth, William P   +9 more
core   +1 more source

The Role of Hematopoietic Cell Transplantation in Ataxia‐Telangiectasia

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Background Ataxia‐telangiectasia (A‐T) is a DNA repair disorder characterized by neurodegeneration, immunodeficiency, and cancer predisposition. Hematopoietic cell transplantation (HCT) is an established therapy in related disorders such as Fanconi anemia (FA) and Nijmegen breakage syndrome (NBS), but its role in A‐T is unclear.
Laila Alkhouli   +3 more
wiley   +1 more source

Ring Expansion of Vinylaziridines through the Strain-Release Pericyclic Reaction: Recent Developments and Applications

open access: yesMolecules, 2013
Recent syntheses of azetidines, pyrrolidines, piperidines and azepines through cycloaddition or sigmatropic rearrangements of vinylaziridines are described. Applications to natural product synthesis and mechanistic investigations are also summarized.
Yu Mi Heo, Seung-Mann Paek
doaj   +1 more source

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