Results 81 to 90 of about 21,334,376 (275)

Multifunctional Bamboo Based Materials Empowered by Multiscale Hierarchical Structures—A Critical Review

open access: yesAdvanced Materials, EarlyView.
This review summarizes the latest progress in transforming renewable bamboo resources into high‐value functional materials. It emphasizes how to leverage bamboo's multiscale hierarchical structures to realize innovative applications in energy, construction, environment, and medicine, providing key insights for developing high‐performance bio‐based ...
Yuxiang Huang   +13 more
wiley   +1 more source

Unlocking the Essence of Lignin: High‐Performance Adhesives That Bond via Thiol‐Catechol Connectivities and Debond on Electrochemical Command

open access: yesAdvanced Materials, EarlyView.
A novel lignin‐inspired adhesive is presented, that combines the bonding strength of a structural adhesive with on‐demand electrochemical debonding, enabled by biomimetic thiol‐catechol connectivities. Voltage application of only 9 V facilitates electrochemical oxidation of catechols to quinones leading to guided detachment on command.
Keven Walter   +7 more
wiley   +1 more source

Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds

open access: yesGreen Synthesis and Catalysis, 2021
An efficient procedure to access to ortho-SCF3 substituted benzophenones from arynes and trifluoromethylthioesters has been developed under transition-metal free conditions. This difunctionalization process involves the first insertion of arynes into the
Chengyao Kimmy Cao   +2 more
doaj   +1 more source

Visible‐Light‐Promoted Dearomatization for The Construction of Imidazole Scaffolds

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Lighting up flat aromatics: a visible‐light photocatalytic dearomative acylation of imidazo[1,2‐a]pyridines using α‐keto acids as sustainable acyl radical precursors is reported, leading to dual fluorescent imidazoles. Dearomatization is a powerful strategy for constructing complex carbocycles and heterocycles, though it typically relies on harsh ...
Silvia Roscales, Aurelio G. Csáky
wiley   +1 more source

Recent Advances in Ene Reactions with Carbon Enophiles

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley   +1 more source

A novel pathway for lipid biosynthesis: the direct acylation of glycerol

open access: yesJournal of Lipid Research, 2001
The acylation of glycerol-3-phosphate by acyl-CoA is regarded as the first committed step for the synthesis of the lipoidal moiety in glycerolipids. The direct acylation of glycerol in mammalian tissues has not been demonstrated.
Douglas P. Lee   +6 more
doaj   +1 more source

Lipoprotein N-Acylation in Staphylococcus aureus Is Catalyzed by a Two-Component Acyl Transferase System

open access: yesmBio, 2020
Bacterial lipoproteins (Lpps) are a class of membrane-associated proteins universally distributed among all bacteria. A characteristic N-terminal cysteine residue that is variably acylated anchors C-terminal globular domains to the extracellular surface,
John H. Gardiner   +5 more
doaj   +1 more source

Proteome-Scale Analysis of Protein S-Acylation Comes of Age.

open access: yesJournal of Proteome Research, 2020
Protein S-acylation (commonly known as palmitoylation) is a widespread reversible lipid modification, which plays critical roles in regulating protein localization, activity, stability, and complex formation.
Yang Wang, Wei Yang
semanticscholar   +1 more source

Proofreading of Noncognate Acyl Adenylates by an Acyl-Coenzyme A Ligase

open access: yesChemistry & Biology, 2013
Aminoacyl-tRNA synthetases remove (proofread) incorrect substrates and thereby prevent errors in protein synthesis. We report enzyme-catalyzed pretransfer editing by pimeloyl-coenzyme A (CoA) ligase (BioW), a biotin synthetic enzyme that converts pimelate, a seven-carbon dicarboxylic acid, to its CoA ester.
Miglena Manandhar, John E. Cronan
openaire   +3 more sources

Intrinsic Photo‐Crosslinkable Semiconductive Small‐Molecule Crystals (i‐PSSCs) for Patterning Electronic Devices

open access: yesAdvanced Science, EarlyView.
A novel intrinsic photo‐crosslinkable semiconductive small molecule is designed and synthesized. The solution‐processed crystalline film can be patterned by in situ photopolymerization under UV light irradiation without external crosslinking agents, and the crystalline order and charge transport properties are preserved, demonstrating potential for ...
Huaqing Li   +7 more
wiley   +1 more source

Home - About - Disclaimer - Privacy