Results 161 to 170 of about 11,269 (219)

Photoswitch dissociation from a G protein-coupled receptor resolved by time-resolved serial crystallography. [PDF]

Nat Commun
Glover H, Saßmannshausen T, Bertrand Q, Trabuco M, Slavov C, Bacchin A, Andres F, Kondo Y, Stipp R, Wranik M, Khusainov G, Carrillo M, Kekilli D, Nan J, Gonzalez A, Cheng R, Neidhart W, Weinert T, Leonarski F, Dworkowski F, Kepa M, Wachtveitl J, Hennig M, Standfuss J.   +23 more
europepmc   +1 more source

Weak‐Solvent‐Coordination Inducing MnNCN Preferential Orientation Toward High‐Capacity and Fast‐Charge Lithium‐Ion Storage

Carbon Energy, EarlyView.
Preferentially oriented MnNCN nanosheets with high active (003) facets were synthesized by an aqueous weak solvent‐coordination strategy, and highly integrated MnNCN/CNT composite was in‐situ constructed as a high‐capacity fast‐charging anode. NCM811//MnNCN/CNT pouch cell exhibits a high energy density of 325 Wh kg−1 with a long cycle‐life over 200 ...
Penghui Guo, Chongteng Wu, Mengying Guo, Xing Shen, Yiming Zhang, Junying Li, Jizhuang He, Jingze Guo, Jing Wang, Yufeng Luo, Weiyou Yang, Guoqiang Tan   +11 more
wiley   +1 more source

The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes

Chemistry – A European Journal, EarlyView.
Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley   +1 more source

Spotlight on the Nucleotide: Solid‐State NMR for the Investigation of ATP Hydrolysis in the ATPase SmsC

Chemistry – A European Journal, EarlyView.
Nucleotide‐detected solid‐state NMR has been applied to probe nucleotide conformations and dynamics during ATP hydrolysis using the dimeric P‐loop ATPase SmsC as a model protein. The different stages of ATP hydrolysis have been mimicked by ATP analogues for which different degrees of conformational heterogeneity have been observed. ABSTRACT Solid‐state
Nina Wehr, Laure Decamps, Julius Schlüter, Koen Linssen, Georg Künze, Kushal Sengupta, Serena DeBeer, Thomas Wiegand   +7 more
wiley   +1 more source

TORO Indexer: a PyTorch-based indexing algorithm for kilohertz serial crystallography. [PDF]

J Appl Crystallogr
Gasparotto P, Barba L, Stadler HC, Assmann G, Mendonça H, Ashton AW, Janousch M, Leonarski F, Béjar B.   +8 more
europepmc   +1 more source

Routes to Cyclobutadiene and Cycloallyl Pt(II) Complexes: Dicationic Bis(Alkyne) Species as Intermediates

Chemistry – A European Journal, EarlyView.
This work demonstrates the synthesis of cationic Pt(II) η3‐cycloallyl complexes, and experimental and computational studies show a ligand bite‐angle dependence of their formation rates. The reactivity of these complexes with Brønsted acids was investigated, leading to the formation of cationic and dicationic Pt(II) η4‐cyclobutadiene complexes ...
Ouchan He, Froze Jameel, Y. Einar H. Stampehl, Liza M. Richter, Matteo Tosi, Martin Kaupp, Thomas Braun   +6 more
wiley   +1 more source

Sheet-on-sheet fixed target data collection devices for serial crystallography at synchrotron and XFEL sources. [PDF]

J Appl Crystallogr
Doak RB, Shoeman RL, Gorel A, Niziński S, Barends TRM, Schlichting I.   +5 more
europepmc   +1 more source

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

Chemistry – A European Journal, EarlyView.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal, Alexandre Millanvois, Louis Fensterbank, Cyril Ollivier   +3 more
wiley   +1 more source

A snapshot love story: what serial crystallography has done and will do for us. [PDF]

Acta Crystallogr D Struct Biol
Henkel A, Oberthür D.
europepmc   +1 more source

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

Chemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes, Nia Foster, Saima Ansari, Paul Kavanagh, Paul Dingwall, Peter C. Knipe   +5 more
wiley   +1 more source