Results 191 to 200 of about 29,886 (251)

Real-time data processing for serial crystallography experiments. [PDF]

IUCrJ
White T, Schoof T, Yakubov S, Tolstikova A, Middendorf P, Karnevskiy M, Mariani V, Henkel A, Klopprogge B, Hannappel J, Oberthuer D, De Gennaro Aquino I, Egorov D, Munke A, Sprenger J, Pompidor G, Taberman H, Gruzinov A, Meyer J, Hakanpää J, Gasthuber M.   +20 more
europepmc   +1 more source

Hydrogen Atom Transfer: An Intramolecular Main‐Group Metal‐Ligand Cooperative Biradical Pathway

Chinese Journal of Chemistry, EarlyView.
The molecular system consisting of a main‐group metal and a redox‐active ligand, ((2,6‐iPr2C6H3)NC(Me))2AlCl(THF), has been shown to react with azides and diazomethanes, yielding products through both a biradical intermediate and a hydrogen atom transfer process.
Ting Chen, Shaoying Ju, Rui Wei, Weili Yan, Yufen Zhao, Douglas W. Stephan, Yile Wu   +6 more
wiley   +1 more source

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova, Cicely M. Warne, Hugo Pétremand, Laura König‐Mattern, Johannes Stöckelmaier, Chris Oostenbrink, Georg M. Guebitz, Jeremy Luterbacher, Alessandro Pellis   +8 more
wiley   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

European Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair, Marc‐Etienne Moret, Luke A. Wilkinson, Adrian B. Chaplin   +3 more
wiley   +1 more source

Novel fixed-target serial crystallography flip-holder for macromolecular crystallography beamlines at synchrotron radiation sources. [PDF]

J Synchrotron Radiat
Gu DH, Jeong DT, Eo C, Seo PW, Kim JS, Park SY.   +5 more
europepmc   +1 more source

Phosphorescent Platinum(II) Complexes With Diazinedipyrrolide Pincer Ligands: Structure and Photophysical Properties

European Journal of Inorganic Chemistry, EarlyView.
A new family of phosphorescent Pt(II) complexes with pyrimidinedipyrrolide ligands, including a pyrazine analog, was designed and synthesized. Their emission properties can be finely tuned via ligand modification, revealing strong phosphorescence originating from intraligand charge transfer transitions.
Marcela Horáková, Alexandre Rico, Filip Bureš, Pascal le Poul, Sébastien Gauthier, Jiří Váňa, Zdeňka Růžičková, Sylvain Achelle   +7 more
wiley   +1 more source

Photoswitch dissociation from a G protein-coupled receptor resolved by time-resolved serial crystallography. [PDF]

Nat Commun
Glover H, Saßmannshausen T, Bertrand Q, Trabuco M, Slavov C, Bacchin A, Andres F, Kondo Y, Stipp R, Wranik M, Khusainov G, Carrillo M, Kekilli D, Nan J, Gonzalez A, Cheng R, Neidhart W, Weinert T, Leonarski F, Dworkowski F, Kepa M, Wachtveitl J, Hennig M, Standfuss J.   +23 more
europepmc   +1 more source

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

European Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki, Frank W. Heinemann, Leonardo D. Slep, Alejandro Cadranel   +3 more
wiley   +1 more source

Phosphoryl Halogen and Hydrogen Bonding Controls the Solid‐State Structures of Aryl Halide‐Containing Phosphonates

European Journal of Inorganic Chemistry, EarlyView.
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross, Paweł Horeglad, Bastian Grabe, Wolf Hiller, Vito Lippolis, Massimiliano Arca, Klaus Jurkschat   +6 more
wiley   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source