ChemBioChem, EarlyView.When placed in the middle of a double helix as a nucleobase surrogate, pyren‐1‐ylpyridine and its palladacyclic derivative show fluorescence emission sensitive to the identity of the canonical nucleobase opposite to it. Emission of the palladacycle is weaker but the base discrimination stronger, possibly because of Pd(II)‐mediated base pairing.
Dattatraya Uttam Ukale, Tuomas Lönnberg
wiley +1 more source
Mass spectrometry dataset of conventional and organic tempe before and after <i>in vitro</i> digestion. [PDF]
Data BriefMio Asni NS +6 more
europepmc +1 more source
Rivalling Self‐Oxidation and Aldehyde Deformylation by a Dinuclear Copper(II)‐Superoxide Complex
ChemCatChem, EarlyView.A dinuclear Cu2L2‐O2•− reactive intermediate stabilized by a tetradentate N3O ligand set is postulated to be at the origin of aldehyde deformylation via a Baeyer‐Villiger oxidation mechanism, while enabling a radical self‐oxidation cascade in the absence of the substrate.
Andrea Squarcina +4 more
wiley +1 more source
Accurate Quantification of Multifunctional C<sub>2-3</sub> Organosulfates in Atmospheric Aerosols Using Liquid Chromatography-Electrospray Ionization Mass Spectrometry: Overcoming Matrix Effects and Underestimation. [PDF]
Environ Sci TechnolLiang S, Wang Y, Chen H, Chan W, Yu JZ.
europepmc +1 more source
ChemCatChem, EarlyView.The tetra‐coordinated iridium‐motif conjugated porphyrin T‐Ir‐ZnPF, possessing Förster‐type triplet‐to‐singlet energy transfer, produces an efficient cocatalyst‐free photocatalytic hydrogen evolution rate (ηH2) of 5.34 mmol g⁻¹ h⁻¹, whereas hydrogen evolution was not detected for the control porphyrin ZnPF without the iridium‐motif.
Govardhana Babu Bodedla +4 more
wiley +1 more source
ChemElectroChem, Volume 12, Issue 6, March 15, 2025.The first synthesis of thioindigosulfonic acids via sulfonation of the parent dye is presented, together with the evaluation of key electrolytic properties, such as solubility and charge transfer characteristics. Investigations conducted in a flow cell demonstrated stable performance over 200 charge/discharge cycles without crossover or degradation ...
Stina Bauer +3 more
wiley +1 more source
Rapid Multi-Omics for Bacterial Identification Using Flow Injection-Ion Mobility-Mass Spectrometry. [PDF]
Anal ChemHynds HM, Carpenter JM, Hines KM.
europepmc +1 more source
Cationic Phosphino Beryllium Scorpionates and their Reactivity as Lewis Acid–Base Pairs
ChemistryEurope, EarlyView.Monocationic tris(pyrazolyl)borate beryllium phosphine complexes are synthesized and characterized. These compounds readily react with substrates like CO2, SO2, H2, O2, S8, and Se8. Therefore, the nature of the BeP bond is also analyzed computationally. Herein, the article describes a facile and modular access to cationic beryllium phosphine complexes
Chantsalmaa Berthold +5 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Detergent design parameters determine experimental successes in membrane protein research. Recent progresses in detergent chemistry are reviewed to promote the top‐down design of non‐ionic detergents for the purification and analysis of intact membrane proteins, including lipid interactions.
Katharina Alker +2 more
wiley +1 more source
Capillary Electrophoresis Electrospray Ionization Mass Spectrometry Reveals Metabolic Perturbations During Nematode Infection in <i>Drosophila melanogaster</i>. [PDF]
MoleculesTuani YT +6 more
europepmc +1 more source