Results 161 to 170 of about 30,977 (246)

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth

open access: yesAngewandte Chemie, EarlyView.
Driven by the mechanistic debate of Bi‐catalyzed CO2‐to‐HCOOH conversion, ambiguity remains regarding true reaction pathways. To resolve this, we combined constant‐potential AIMD simulations with spectroscopic evidence to analyze the competitive pathways.
Hyun Dong Jung   +4 more
wiley   +2 more sources

Enriched and Sustained Oxygen Vacancies in Amorphous NiWOx Enhance and Stabilize Urea Electrooxidation

open access: yesAngewandte Chemie, EarlyView.
We propose an “amorphous oxygen mechanism (AOM)” for urea electrooxidation on amorphous NiWOx with tunable Ov, which achieves robust UOR activity and stability simultaneously. The “amorphous oxygen” in NiWOx prefers to escape during the UOR, in situ generating and stabilizing Ov, which thermodynamically promotes the reaction.
Yinuo Wang   +9 more
wiley   +2 more sources

Silkworm Pupae Function as Efficient Producers of Recombinant Glycoproteins with Stable-Isotope Labeling. [PDF]

open access: yesBiomolecules, 2020
Yagi H   +9 more
europepmc   +1 more source

A Wagner–Meerwein‐Like Rearrangement Generates a Vinyl Group in the Biosynthesis of the Polychlorinated Lipopeptides Fischerazoles

open access: yesAngewandte Chemie, EarlyView.
The fischerazoles, unusual cyanobacterial chlorinated lipopeptides are reported. During their biosynthesis, a linear fatty acyl‐acyl carrier protein (ACP) precursor is rearranged through the action of the S‐adenosyl‐methionine (SAM)‐dependent methyltransferase FshF, to generate a pendant vinyl group.
Sandra A. C. Figueiredo   +8 more
wiley   +2 more sources

4-plex quantitative glycoproteomics using glycan/protein-stable isotope labeling in cell culture. [PDF]

open access: yesJ Proteomics
Jiang P   +5 more
europepmc   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

open access: yesAngewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du   +10 more
wiley   +2 more sources

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