Angewandte Chemie International Edition, EarlyView.The strobilurin iterative PKS assembles a remarkable EZE triene by varying its stereoselectivity during synthesis. Stereoselective 2R‐methylation of the triketide intermediate by the C‐terminal C‐methyltransferase domain induces the KR and DH domains to invert their native stereoselectivities and produce a Z‐configured intermediate.
Maurice Hauser +5 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2012 Mycoplasma fermentans possesses unique α-glycolipid antigens (GGPL-I and GGPL-III) at the cytoplasm membrane, which carry a phosphocholine group at the sugar primary (6-OH) position.
Yoshihiro Nishida +6 more
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Stereochemical outcomes of C–F activation reactions of benzyl fluoride
Beilstein Journal of Organic Chemistry, 2018 In recent years, the highly polar C–F bond has been utilised in activation chemistry despite its low reactivity to traditional nucleophiles, when compared to other C–X halogen bonds.
Neil S. Keddie +4 more
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Five-membered ring annelation in [2.2]paracyclophanes by aldol condensation
Beilstein Journal of Organic Chemistry, 2014 Under basic conditions 4,5,12,13-tetraacetyl[2.2]paracyclophane (9) cyclizes by a double aldol condensation to provide the two aldols 12 and 15 in a 3:7 ratio.
Henning Hopf +2 more
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The Stereochemistry and Reactivity of Metal-Schiff Base Complexes. III. The Kinetic and Thermodynamic Stereoselectivities in the Formation of N,N′-Ethylenebis(α-methylsalicylideneaminato)cobalt(III)Complexes with
, 1980 Yuki Fujii +3 more
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On the Stereochemistry of Lignin Model Compounds of the 1,2-Diaryl-1,3-propanediol Type. The Crystal Structure of erythro-2-(4-Methoxyphenyl)-1-phenyl-1,3-propanediol. [PDF]
, 1987 Knut Lundquist +3 more
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Stereochemical Research on Cembranes Diterpenoid Sinulariol Z Based on Residual Dipolar Couplings
Chinese Journal of Magnetic ResonanceResearch on the stereochemistry of natural products, especially that of flexible macrocyclic molecules, has always been a huge challenge. Cembranes diterpenoids are a typical class of flexible macrocyclic molecules, whose configurations are often ...
SHI Xing +3 more
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Identification of Components of the Aggregation Pheromone of the Guam Strain of Coconut Rhinoceros Beetle, Oryctes rhinoceros, and Determination of Stereochemistry [PDF]
, 2021 David R. Hall +4 more
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