Results 71 to 80 of about 58,537 (265)

Quiralidade em moléculas e cristais Chirality at molecules and crystals

open access: yesQuímica Nova, 2009
The present contribution describes some concepts of stereochemistry and chirality in molecules and crystals. This paper also reports on the development of a simple and fast experiment to prepare and recognize conglomerate and true racemate of tartaric ...
Ayres Guimarães Dias   +1 more
doaj   +1 more source

Genomics-inspired discovery of massiliachelin, an agrochelin epimer from Massilia sp. NR 4-1

open access: yesBeilstein Journal of Organic Chemistry, 2019
A putative siderophore locus was detected in the genome of the violacein-producing bacterium Massilia sp. NR 4-1 and predicted to direct the biosynthesis of a molecule that is structurally related to the thiazoline-containing siderophore micacocidin.
Jan Diettrich   +2 more
doaj   +1 more source

A Benchmark of Density Functional Approximations For Thermochemistry and Kinetics of Hydride Reductions of Cyclohexanones

open access: yesChemistryOpen, 2019
The performance of density functionals and wavefunction methods for describing the thermodynamics and kinetics of hydride reductions of 2‐substituted cyclohexanones has been evaluated for the first time.
Xavier Deraet   +5 more
doaj   +1 more source

A detailed view on 1,8-cineol biosynthesis by Streptomyces clavuligerus

open access: yesBeilstein Journal of Organic Chemistry, 2016
The stereochemical course of the cyclisation reaction catalysed by the bacterial 1,8-cineol synthase from Streptomyces clavuligerus was investigated using stereospecifically deuterated substrates.
Jan Rinkel   +3 more
doaj   +1 more source

Crystal structure, computational study, and Hirshfeld analysis of exo-1,2,3,5-tetraphenyl-1a',9b'-dihydrospiro[bicyclo[3.1.0]hexane-6,1′-cyclopropa[l]phenanthren]-2-en-4-one

open access: yesActa Crystallographica Section E: Crystallographic Communications
The reaction of dibenzonorcarynyliden(e/oid) with phencyclone was recently reported to give a congested spiropentane with endo stereochemistry. Herein we report that, in sharp contrast, an analogous reaction using tetracyclone, instead of phencyclone ...
Alexander D. Roth, Dasan M. Thamattoor
doaj   +1 more source

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