Results 81 to 90 of about 118,878 (273)

On the mechanism of Dehydroquinate synthase : a thesis presented to Massey University in partial fulfilment of the requirements for the degree of Master of Science in Chemistry [PDF]

open access: yes, 2001
The aim of this thesis is to investigate the influence of fluorine substitution on the second reaction of the shikimate pathway catalysed by the enzyme 3-dehydroquinate synthase.
Kathirgamanathan, Kalyani
core  

STRUCTURE OF METHYLPHEOPHORBIDE-RCI [PDF]

open access: yes, 1986
he methanolic extract of the cyanobacterium (blue-green alga) Spirulina geitleri has been treated with methanolic acid to convert all chlorophyllous pigments to their methylpheophorbides.
Budzikiewicz H.   +27 more
core   +1 more source

Dynamic Reactivity: Reversible Reaction of a Phosphinine–Borane Adduct With Water and Double Hydrophosphination

open access: yesChemistry – A European Journal, EarlyView.
A phosphinine–borane Lewis pair shows a dynamic mode of water addition, revealing reversible and regioselective transformations that expand the reactivity of aromatic phosphorus heterocycles and open pathways to stimuli‐responsive systems for catalysis, small‐molecule activation, and functional materials.
Samantha Frank   +7 more
wiley   +1 more source

Integrated X-Ray, NMR, ECD, and Computational Approaches to Assign the Stereochemistry of Nortriterpenoids

open access: yesNatural Product Communications, 2019
Highly oxygenated nortriterpenoids are the principle bioactive chemical constituents isolated from plants of the genera Schisandra and Kadsura . The stereochemistry of these molecules remains a highly challenging problem to solve.
Xiaojuan Wang, Mark T. Hamann
doaj   +1 more source

Free radical 5-exo-dig cyclization as the key step in the synthesis of bis-butyrolactone natural products: experimental and theoretical studies [PDF]

open access: yes, 2011
Radical cyclization reactions were performed by 5-exo-dig mode to yield cis-fused bicyclic systems, leading to the synthesis of bis-butyrolactone class of natural products.
Allinger   +23 more
core   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Polarimetry and stereochemistry: the optical rotation of Vitamin C as a function of pH

open access: yesEducación Química, 2015
A novel experiment was prepared to help chemistry educators to improve the stereochemistry curriculumof secondary school students and undergraduate students.
Johan A. Linthorst   +1 more
doaj   +1 more source

Studies on the synthesis of α−iodoaziridines and improved conditions for the synthesis of alkyl-α-iodoaziridines using ClMgCHI2 [PDF]

open access: yes, 2015
α-Iodoaziridines are unusual motifs and intriguing structures for further functionalisation of the intact aziridine. The preparation of N-protected α-iodoaziridines is achieved through an addition-cyclisation reaction of LiCHI2 with imines.
Affron, DA, Boultwood, T, Bull, JA
core   +1 more source

Cationic Permethylated Cyclodextrins Capable of Self‐Assembling Into Linear Nanostructures in Water

open access: yesChemistry – A European Journal, EarlyView.
A quaternary ammonium bridge equipped with a lipophilic substituent in permethylated cyclodextrins suppresses undesired supramolecular interactions and promotes controlled, directional head‐to‐tail self‐assembly into well‐defined linear nanostructures.
Maxime Kolb   +4 more
wiley   +1 more source

Organic chemistry lecture course and exercises based on true scale models

open access: yesChemistry Teacher International, 2020
3D models of chemical structures are an important tool for chemistry lectures and exercises. Usually, simplified models based on standard bond length and angles are used.
Lederle Felix, Hübner Eike G.
doaj   +1 more source

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