Results 91 to 100 of about 20,087 (300)

Tunable polylactide plasticizer design: Rigid stereoisomers

open access: hybrid, 2021
Wenxiang Xuan   +2 more
openalex   +1 more source

The Chemistry of Subphthalocyanines: Synthetic Strategies for their Axial, Peripheral, and Remote Postfunctionalization

open access: yesChemistryEurope, EarlyView.
From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez   +4 more
wiley   +1 more source

THE STRUCTURE AND CONFORMATION OF LIGNIN AS JUDGED BY X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS OF LIGNIN MODEL COMPOUNDS: ARYLGLYCEROL -SYRINGYL ETHERS

open access: yesBioResources, 2009
Structural elements of the arylglycerol -syringyl ether type are very frequent in hardwood lignins. A variety of crystalline dimeric lignin models representing different diastereomeric forms of structural elements in lignin of this type have been ...
Knut Lundquist   +2 more
doaj  

Synthesis of α‐Pentafluorosulfanylated‐β2,3‐Amino Esters

open access: yesChemistryEurope, EarlyView.
De novo α‐SF5‐β2,3‐amino esters are now accessible through a straightforward aza‐Michael reaction using a series of newly developed (E)‐α‐SF5‐α,β‐unsaturated esters. Two new, highly functionalized, contiguous tertiary stereocenters are formed with diastereodivergence governed by the choice of solvent and/or base.
Thi Mo Nguyen   +5 more
wiley   +1 more source

Computational insights into the stereo-selectivity of catechins for the inhibition of the cancer therapeutic target EGFR kinase

open access: yesFrontiers in Pharmacology
The epidermal growth factor receptor (EGFR) plays a crucial role in regulating cellular growth and survival, and its dysregulation is implicated in various cancers, making it a prime target for cancer therapy.
Mohd Rehan   +12 more
doaj   +1 more source

Isomerism as Manifestation of Intrinsic Symmetry of Molecules: Lunn–Senior’s Theory [PDF]

open access: yes, 2009
This article presents the principal results of the doctoral thesis “Isomerism as internal symmetry of molecules” by Valentin Vankov Iliev (Institute of Mathematics and Informatics), successfully defended before the Specialised Academic Council for ...
Iliev, Valentin
core  

Imidazoline‐Proline and Imidazoline‐Prolinate Ligands for Copper‐Catalyzed Asymmetric Exo‐Selective [3 + 2] Cycloaddition of Iminoesters with Nitroalkenes

open access: yesChemistryEurope, EarlyView.
From a modular synthesis of nonphosphine chiral nitrogen‐based chiral imidazoline–amino acid ligands, two new chiral imidazoline–proline‐copper catalysts are developed for targeting exo‐selective [3 + 2] cycloaddition reaction. Density functional theory studies rationalize the observed stereoselectivity and the distinct chiral pockets of the two ...
Yan Yu   +4 more
wiley   +1 more source

Gold(I)‐Catalyzed Domino Cyclization for the Construction of Trispirocyclic Cyclohexanes

open access: yesChemistryEurope, EarlyView.
We describe herein a series of intricate trispirocyclic architectures that have been synthesized from readily available substrates through an operationally simple one‐pot transformation under mild conditions. An unprecedented gold(I)‐catalyzed domino cyclization involving 2‐ethynylbenzyl alcohol derivatives and heterocyclic α,β‐unsaturated imines ...
Manon Genet   +3 more
wiley   +1 more source

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