Results 111 to 120 of about 36,653 (344)

Total Synthesis of Kanamycins

open access: yesChemistry – A European Journal, EarlyView.
This paper reports on creating a novel synthetic route of kanamycins A and B using the desymmetric boron‐mediated aglycon delivery (BMAD) reaction of meso‐diol acceptor with 1,2‐anhydro donor and regio‐ and stereoselective glycosylation of diol acceptor with trichloroacetimidate donor for introduction of a set of challenging 1,2‐cis‐glycosidic linkages
Kanae Hosomi   +7 more
wiley   +1 more source

Coordination Compounds and Complex Ions [PDF]

open access: yes, 1965
Coordination compounds and complex ions are an important and practical part of fundamental chemistry.
Nelson, Carole
core   +1 more source

S‐Containing Double Helicenes Featuring Robust Radical Cations

open access: yesChemistry – A European Journal, EarlyView.
This study introduces two S‐containing double helicenes with robust radical cations. X‐ray crystallography shows twisted conformations matching DFT‐calculated minima. Chemical oxidation of these double helicenes produced π‐conjugated radical cations, which remained stable in solution for weeks.
Li Zhang   +7 more
wiley   +1 more source

Exploring the Impact of Phenanthroline‐Based Glycoconjugated Ru(II) Polypyridyl Photosensitizers on Metastasis‐Related Processes

open access: yesChemistry – A European Journal, EarlyView.
A novel family of water‐soluble, nontoxic, and phosphorescent N‐glycosylated Ru(II) phenanthroline‐based complexes are reported. They exhibit photoselectivity indexes ranging from 10 to 44 in PC‐3 cells, while impacting cell migration and resistance to detachment after irradiation with blue light.
Elena de la Torre‐Rubio   +5 more
wiley   +1 more source

THE STRUCTURE AND STEREOISOMERISM OF THREE MITRAGYNA ALKALOIDS [PDF]

open access: bronze, 1960
J. C. Seaton   +3 more
openalex   +1 more source

Influence of the Substitution Pattern of Terpene‐Based Seven‐Membered Lactones on Yttrium‐Mediated Ring‐Opening Polymerization: A Kinetic and Mechanistic Investigation

open access: yesChemistry – A European Journal, EarlyView.
(‐)‐Menthide and trans (+)‐carvomenthide, differing only in substitution pattern, were polymerized via ROP using a bis(phenolate) yttrium catalyst. Kinetic studies showed faster polymerization of (+)‐carvomenthide but greater control with (‐)‐menthide. Experimental and DFT analyses revealed mechanistic differences in chain propagation, highlighting how
Lea‐Sophie Hornberger   +7 more
wiley   +1 more source

Glycans and Chirality: Stereoselectivity at the Core of DC‐SIGN's Recognition. A Novel View of the Optimum Minimal Ligand Epitope

open access: yesChemistry – A European Journal, EarlyView.
The stereochemical diversity of the “glycan code” enables similar chiral motifs to arise from both D‐ and L‐sugars. Focused on DC‐SIGN–glycan recognition, two diverse monosaccharide scaffolds, D‐Man (D‐Rha) and L‐Gal (L‐Fuc), maintain the exquisite stereochemistry encoded in the minimal binding epitope.
J. Daniel Martínez   +7 more
wiley   +1 more source

The Ascent of Supramolecular Polymers and Gels in Asymmetric Catalysis

open access: yesChemistry – A European Journal, Accepted Article.
Supramolecular polymers and gels, formed by the spontaneous assemblies of small molecules through various types of non‐covalent interactions, are attractive materials for many applications. Their modularity also offers many opportunities in asymmetric catalysis, that have been tackled in the last two decades and more intensively in the last one.
Ran Chen   +2 more
wiley   +1 more source

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