Mechanistic Elucidation and Stereochemical Consequences of Alternative Binding of Alkenyl Substrates by Engineered Arylmalonate Decarboxylase. [PDF]
van der Pol E +14 more
europepmc +1 more source
Stereo-reversed E2 unlocks <i>Z</i>-selective C-H functionalization. [PDF]
Verardi PJ +10 more
europepmc +1 more source
Larger Substituents Enhance Stereospecificity in 1,1-Diazene Nitrogen Extrusion through Attenuation of Dynamic Mismatching. [PDF]
Wu RK, Zhang SQ, Hong X.
europepmc +1 more source
A radical strategy to the synthesis of bicyclo[1.1.1]pentyl <i>C</i>-glycosides. [PDF]
Goti G +6 more
europepmc +1 more source
Supramolecular protecting groups can impart prosthetic stereoselectivity to catalytic systems employing unmodified achiral heterogenous catalysts. [PDF]
Vergara-Arenas BI +2 more
europepmc +1 more source
A method for synthesizing sulfur‐substituted cyclohexenes is reportedthat leverages the η2‐coordination of a phenyl sulfone to [WTp(NO)(PMe3)] (Tp = trispyrazolylborate). Three sequential protonation and nucleophilic additions to the bound arene, followed by oxidative decomplexation, affords functionalized cyclohexenes bearing sp3‐ and sulfur‐enriched ...
Daniel J. Siela +3 more
wiley +1 more source
NaHMDS/B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-promoted diastereoselective Friedel-Crafts alkylation of indoles/pyrroles with <i>N-tert</i>-butanesulfinylimines: towards the asymmetric synthesis of bisindole alkaloid Calcicamide B. [PDF]
Zhang G +11 more
europepmc +1 more source
Organic and Metallacages for Chemical Sensing: Progress in Water‐Compatible Systems
Supramolecular cages function as three‐dimensional receptors for selective molecular recognition and sensing, and this review outlines design principles for water‐stable architectures, key analyte‐ and medium‐dependent challenges, recent water‐compatible examples (including polymer‐integrated systems), and future opportunities for cage‐based ...
Rabia Zahid +4 more
wiley +1 more source
Woollins’ Reagent: A Graphical Review of Its Main Synthetic Uses
João V. X. da Silva +2 more
doaj +1 more source
Approaches to stereoselective 1,1'-glycosylation. [PDF]
Zucchetta D, Zamyatina A.
europepmc +1 more source

