Nonenzymatic, Prebiotic Aminoacylation Couples Chirality of RNA and Protein. [PDF]
Davisson JA +8 more
europepmc +1 more source
Competing Charge Transport Pathways: A Spirobifluorene‐Based Molecular Loop
A rigid molecular loop integrating a spirobifluorene (SBF) core with a cycloparaphenylene (CPP) moiety provides two distinct transport channels. Through‐space spiroconjugation and radial π‐conjugation along a CPP backbone coexist within a single molecule.
Brian Ogi +4 more
wiley +1 more source
Catalytic [6 + 3] cycloaddition for the synthesis of medium-sized ring systems: a critical review. [PDF]
Archna +4 more
europepmc +1 more source
Synthesis of Naphthoquinones by Pd‐Catalyzed Heck–Matsuda Arylation of Lapachol
Direct Heck–Matsuda arylation of lapachol enables the efficient synthesis of diverse naphthoquinones under homogeneous and heterogeneous palladium catalysis. The methodology features broad substrate scope, gram‐scale applicability, and provides a practical platform for quinone diversification.
Breno U. de Abreu +13 more
wiley +1 more source
Discovery of a Plant Pictet-Spenglerase With R-Stereoselectivity. [PDF]
Morweiser C +3 more
europepmc +1 more source
A Straightforward Synthesis of Benzestrol by Matteson Homologation Using Chiral Benzyl Carbamates
Benzestrol can easily be obtained stereoselectively via Matteson reaction using chiral Boronic esters and chiral benzyl carbamates. A straightforward and highly stereoselective synthesis of the non‐steroidal estrogen benzestrol is described based on Matteson homologations.
Max Benjamin Becker, Uli Kazmaier
wiley +1 more source
Umpolung Character of Styrenes: Mechanism and Stereoselective Studies of α, β-Substituted Amino Acids Using Chiral Ir-Phosphine Complexes. [PDF]
Bhaskararao B, Antonio JJ, Kraka E.
europepmc +1 more source
The Expanding Role of Diazirines in Synthetic Methodology
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic +3 more
wiley +1 more source
Stereoselective <i>O</i>‑Furanosylation of Phenols by Cooperative Effect of Lewis Acid and Nickel Complex. [PDF]
Fang S +7 more
europepmc +1 more source

