Selective and Tunable Routes for Glucose to Fructose Conversion Using MgCl2 Catalysis and Comparison to Other Metal Ions [PDF]
ChemistryOpenMgCl2 is a cheap catalyst for glucose to fructose conversion in water with excellent selectivity if competing pathways leading to CC bond breakage avoided by control of pH and oxygen and use of mild temperatures. Both a stereoselective 1,2‐hydride shift and isomerization via an enediol intermediate contribute to the isomerization.
Maragani R, Meier S.
europepmc +2 more sources
Schiff based derived homogeneous catalysts for ring‐opening terpolymerization
Polymer International, EarlyView.One‐pot synthesis of degradable terpolymers from l‐lactide, propylene oxide and CO₂ using diverse catalysts is described, revealing structure–property relationships for tailored applications in sustainable materials. Abstract In this study, we synthesized and evaluated a series of Schiff base cobalt catalysts for the terpolymerization of propylene ...
Akanksha Ranade, Amjad Ali, Rajeev Mehta
wiley +1 more source
Iron-Catalyzed Tunable Double Bond Migration and Geometrical Isomerization in Olefins via a Spin-Accelerated Alkyl Mechanism. [PDF]
Angew Chem Int Ed EnglObeid AH +3 more
europepmc +1 more source
The continuing significance of chiral agrochemicals
Pest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley +1 more source
Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO<sub>2</sub> reintegration. [PDF]
Sci AdvXia J +7 more
europepmc +1 more source
Drivers of strigolactone diversity: P450s in strigolactone biosynthesis
Journal of Integrative Plant Biology, EarlyView.This review summarizes the discovery and functional identification of cytochrome P450 in strigolactone biosynthesis, classifies and summarizes the members discovered so far, clarifies their biological significance, discusses the technology of strigolactone synthesis research, and finally describes some problems in strigolactone research and potential ...
Changbin Niu +2 more
wiley +1 more source
Hexafluoroisopropanol-Promoted Stereospecific Glycosylation Enables Efficient Access to N-O-Linked 1,2-<i>cis</i>-2-Amino Glycosides. [PDF]
JACS AuCheng Y, Su R, Tao X, Xue XS, Dai Y.
europepmc +1 more source
Osmium‐Catalyzed Dihydroxylation of 1,2‐Dioxines: A New Entry for Stereoselective Sugar Synthesis.
, 2007 Tony V. Robinson +2 more
openalex +2 more sources
Heterogeneity of iridoid biosynthesis in catmints: Molecular background in a phylogenetic context
Journal of Integrative Plant Biology, EarlyView.Evolutionary gains and losses of key biosynthetic genes likely resulting from multiple independent evolutionary events explain why certain Nepeta (catnip) species produce both the active, cat‐attracting nepetalactones and sugar‐bound iridoids, while others make only the sugar‐bound forms, and some have lost iridoid production entirely.
Tijana Banjanac +15 more
wiley +1 more source