EFFECT OF LOADING ON SEPARATION EFFICIENCY USING STERIC EXCLUSION CHROMATOGRAPHY.
T. A. Maldacker, L. B. Rogers
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Bio‐Inspired Molecular Events in Poly(Ionic Liquids)
Originating from dipolar and polar inter‐ and intra‐chain interactions of the building blocks, the topologies and morphologies of poly(ionic liquids) (PIL) govern their nano‐ and micro‐processibility. Modulating the interactions of cation‐anion pairs with aliphatic dipolar components enables the tunability of properties, facilitated by “bottom‐up ...
Jiahui Liu, Marek W. Urban
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The Effect of Counteranions on the Polymer Steric Structure in the Cationic Polymerization of α-Methylstyrene [PDF]
Yoshihiko Matsuguma, Toyoki Kunitake
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Dual‐Ligand Metal‐Organic Frameworks via In Situ Amidoxime Engineering for Selective Ion Separation
Inspired by microbial ion‐trapping mechanisms, a mild and universal strategy is developed to construct highly porous amidoxime‐functionalized MOFs. DFT calculations and molecular force measurements reveal that the dual‐ligand amidoxime configuration significantly strengthens Ga(III) affinity.
Zhifang Lv +9 more
wiley +1 more source
Cover Feature: Thermally Induced trans‐to‐cis Isomerization and Its Photoinduced Reversal Monitored using Absorption and Luminescence: Cooperative Effect of Metal Coordination and Steric Substituent (Chem. Eur. J. 20/2019) [PDF]
Jun‐Quan Zhang +5 more
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This study introduces a novel chloro boron subphthalocyanine/polymer blend OFET sensor achieving 0.005 ppb limit of detection for ammonia at room temperature and high selectivity against similar amines. An original theoretical framework is proposed to describe the sensing mechanism, relating analyte molecular volume and Lewis basicity to sensor ...
Kavinraaj Ella Elangovan +6 more
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Structural and Dynamic Origins of Payne Effect Reduction by Steric Stabilization in Silica Reinforced Poly(butadiene) Nanocomposites [PDF]
James M. Hart +7 more
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Visual Immunoassays: Layered Aggregation with Steric Effect: Morphology‐Homogeneous Semiconductor MoS2 as an Alternative 2D Probe for Visual Immunoassay (Small 7/2018) [PDF]
Bang Lin Li +5 more
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Sustainable Catalyst‐Free PLG Networks: Recyclability, Biodegradability, and Functional Performance
A catalyst‐additive free covalent adaptable network is developed from star‐shaped poly(lactide‐co‐glycolide) cross‐linked with pyromellitic dianhydride, enabling internal carboxylic acid‐driven transesterification. The resulting biodegradable network exhibits mechanical robustness (Young's modulus ≈1.6 GPa), complete recyclability, rapid biodegradation
Lars Schwarzer +2 more
wiley +1 more source

