Steric Effect of a Capping Ligand on the Formation of Supramolecular Coordination Networks of Ni(II): Solid-State Entrapment of Cyclic Water Dimer. [PDF]
ACS Omega, 2020 Kumar S, Khullar S, Mandal SK.
europepmc +2 more sources
Ion Steric Effect Induces Giant Enhancement of Thermoelectric Conversion in Electrolyte-Filled Nanochannels. [PDF]
Nano letters (Print), 2023 Ionic thermoelectricity in nanochannels has received increasing attention because of its advantages, such as high Seebeck coefficient and low cost. However, most studies have focused on dilute simple electrolytes that neglect the effects of finite ion ...
Wenyao Zhang +5 more
semanticscholar +1 more source
Steric Effect Tuned Ion Solvation Enabling Stable Cycling of High-Voltage Lithium Metal Battery.
Journal of the American Chemical Society, 2021 1,2-Dimethoxyethane (DME) is a common electrolyte solvent for lithium metal batteries. Various DME-based electrolyte designs have improved long-term cyclability of high-voltage full cells.
Yuelang Chen +10 more
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Micromachines, 2021 In this paper, the combined effect of the fluid rheology, finite-sized ions, and slippage toward augmenting a non-reacting solute’s mass transport due to an oscillatory electroosmotic flow (OEOF) is determined.
Ruben Baños +3 more
doaj +1 more source
Review and Modification of Entropy Modeling for Steric Effects in the Poisson-Boltzmann Equation
Entropy, 2020 The classical Poisson-Boltzmann model can only work when ion concentrations are very dilute, which often does not match the experimental conditions.
Tzyy-Leng Horng
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Redox Potential and Crystal Chemistry of Hexanuclear Cluster Compounds
Molecules, 2021 Most of TM6-cluster compounds (TM = transition metal) are soluble in polar solvents, in which the cluster units commonly remain intact, preserving the same atomic arrangement as in solids.
Elena Levi, Doron Aurbach, Carlo Gatti
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Ferrocenoyl-adenines: substituent effects on regioselective acylation
Beilstein Journal of Organic Chemistry, 2022 A series of N6-substituted adenine–ferrocene conjugates was prepared and the reaction mechanism underlying the synthesis was explored. The SN2-like reaction between ferrocenoyl chloride and adenine anions is a regioselective process in which the product ...
Mateja Toma +5 more
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Metal–Metal Bond in the Light of Pauling’s Rules
Molecules, 2021 About 70 years ago, in the framework of his theory of chemical bonding, Pauling proposed an empirical correlation between the bond valences (or effective bond orders (BOs)) and the bond lengths.
Elena Levi, Doron Aurbach, Carlo Gatti
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Geometric and energetic data from quantum chemical calculations of halobenzenes and xylenes
Data in Brief, 2020 This article presents theoretical data on geometric and energetic features of halobenzenes and xylenes. Data were obtained from ab initio geometry optimization and frequency calculations at HF, B3LYP, MP2 and CCSD levels of theory on 6–311++G(d,p) basis ...
Sopanant Datta, Taweetham Limpanuparb
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Sea Level Seasonal, Interannual and Decadal Variability in the Tropical Pacific Ocean
Remote Sensing, 2021 The satellite altimeter data, temperature and salinity data, and 1.5-layer reduced gravity model are used to quantitatively evaluate the contributions of the steric effect and the dynamic process to sea level variations in the Tropical Pacific Ocean (TPO)
Jianhu Wang +4 more
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