Advanced Materials, EarlyView.A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang +8 more
wiley +1 more source
How electronic and steric effects in acceptor alcohols shape S<sub>N</sub>1- and S<sub>N</sub>2-type glycosylation reactions. [PDF]
Chem SciHoogers D +6 more
europepmc +1 more source
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
Advanced Materials, EarlyView.A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source
Biocatalyzed aza-michael addition <i>via</i> continuous flow technology: a game-changer for the facile synthesis of <i>N-</i>alkylated pyrazole derivatives. [PDF]
RSC AdvDu LH, Yan BL, Xue MM, Wang L, Luo XP.
europepmc +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
Advanced Materials, EarlyView.An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Advanced Porous Materials for Maritime Carbon Capture
Advanced Materials, EarlyView.Carbon capture from emission sources, such as marine vessels, has attracted significant attention over the years. To achieve this goal, sorbents such as metal–organic frameworks (MOFs), porous polymer networks (PPNs), covalent organic frameworks (COFs), and their post‐synthetic modifications are currently being explored.
Kelechi Festus +6 more
wiley +1 more source
A planar chiral organoselenium enabled enantioselective intramolecular oxidation of trisubstituted olefins. [PDF]
Nat CommunZhu W, Fu FY, Xu KY, Zheng WH.
europepmc +1 more source
Recent Advances in Collective Behaviors of Micro/Nanomotor Swarms
Advanced Materials, EarlyView.This review describes the driving forces behind collective motion, explores the self‐organization of micro/nano swarms across zero‐dimensional (0D), one‐dimensional (1D), two‐dimensional (2D), and three‐dimensional (3D) spaces, and highlights their potential in drug delivery, environmental monitoring, and smart devices.
Siwen Sun +4 more
wiley +1 more source
Directing Cation Coordination and Phase in Nickel Sulfide Nanocrystals through the Addition of Phosphines. [PDF]
Chem MaterEndres EJ +3 more
europepmc +1 more source
Advanced Materials, EarlyView.Heptazine‐assisted MR‐TADF emitters enable narrowband yellow emission with high efficiency at high luminance in solution‐processed OLEDs. In doped films, HAP‐3CzBN achieves a record‐fast kRISC of 1.19 × 106 s−1. The optimized HAP‐3CzBN devices deliver 15.5% EQEmax with negligible roll‐off at 1000 cd m−2, 11.2% at 10,000 cd m−2, and a benchmark 20.3 ...
Changfeng Si +5 more
wiley +1 more source