Results 21 to 30 of about 13,761,270 (353)

Steric Effects on Electroosmotic Nano-Thrusters under High Zeta Potentials

open access: yesMathematics, 2021
Here, space electroosmotic thrusters in a rigid nanochannel with high wall zeta potentials are investigated numerically, for the first time, considering the effect of finite size of the ionic species. The effect, which is called a steric effect, is often
Jiaxuan Zheng, Siyi An, Yongjun Jian
doaj   +1 more source

Steric and Stereochemical Modulation in Pyridyl- and Quinolyl-Containing Ligands

open access: yesMolecules, 2016
Nitrogen-containing pyridine and quinoline are outstanding platforms on which excellent ionophores and sensors for metal ions can be built. Steric and stereochemical effects can be used to modulate the affinity and selectivity of such ligands toward ...
Zhaohua Dai
doaj   +1 more source

Kinetics of the reaction of 5-substituted orotic acids with diazodiphenylmethane [PDF]

open access: yesJournal of the Serbian Chemical Society, 2004
Rate konstants for the reaction of eight 5-substituted orotic acids with diazodiphenylmethane (DDM) in dimethylformamide (DMF) were determined at 30 ºC by the known spectrophotometricmethod.
Jovanović Bratislav Ž.   +2 more
doaj   +3 more sources

Electronic integral characteristics of groups in the fluoro-substituted of isobutan and neopentan [PDF]

open access: yesФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов, 2018
Within a «quantum theory of atoms in molecules» (QTAIM) the equilibrium geometry and the electron structure of fluoro-substituted molecules (CH3)2−CH−CH(3-n)Fn and (CH3)3−C−CH(3-n)Fn, where 1 ≤ n ≤ 3, were studied.
A.V. Kotomkin   +3 more
doaj   +1 more source

Controlling the Assembly of PdII/Bianthryl‐Based Monomeric and Dimeric Interlocked Cages by Steric Effects

open access: yesChemistryEurope, 2023
In the energy landscape of coordination‐driven self‐assembly processes, the isolation of kinetically formed supramolecular cages has long been identified as a challenging task.
Sota Watanabe   +3 more
doaj   +1 more source

An NMR Study on How Steric Effects Affect Synergistic Effects in Surfactant Mixtures

open access: yesChinese Journal of Magnetic Resonance, 2018
NMR spectra of aqueous solutions of cetyltrimethylammonium bromide (CTAB)/triton X-100 (TX-100), sodium dodecyl sulfate (SDS)/TX-100 and CTAB/TX-100/SDS surfactant mixtures were acquired.
CHEN Xiao-ying   +4 more
doaj   +1 more source

Topological Steric Effect Index and Its Application. [PDF]

open access: yesChemInform, 2004
This paper proposed a Topological Steric Effect Index (TSEI) of a group based on the relative specific volume of the reaction center screened by the atoms of the substituents. Investigated results show good correlations between the parameter TSEI and the dihedral angles between both phenyl rings determined by photoelectron spectroscopy for 7 ...
Chenzhong, Cao, Li, Liu
openaire   +2 more sources

Steric Effects on Space Electroosmotic Thrusters in Soft Nanochannels

open access: yesMathematics, 2021
The influence of steric effects on the performances of space electroosmotic thrusters (EOTs) was numerically delineated in soft nanochannels for which its walls are covered with polyelectrolyte materials.
Jiaxuan Zheng, Beinan Jia, Yongjun Jian
doaj   +1 more source

Outlining the Roles of Membrane-Foulant and Foulant-Foulant Interactions in Organic Fouling During Microfiltration and Ultrafiltration: A Mini-Review

open access: yesFrontiers in Chemistry, 2020
Membrane fouling remains a notorious problem in microfiltration (MF) and ultrafiltration (UF), and a systematic understanding of the fouling mechanisms is fundamental for solving this problem. Given a wide assortment of fouling studies in the literature,
Hao Xu   +9 more
doaj   +1 more source

Antioxidant and Cytoprotective Effects of Tibetan Tea and Its Phenolic Components

open access: yesMolecules, 2018
Tibetan tea (Kangzhuan) is an essential beverage of the Tibetan people. In this study, a lyophilized aqueous extract of Tibetan tea (LATT) was prepared and analyzed by HPLC.
Hong Xie   +7 more
doaj   +1 more source

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